Hostname: page-component-8448b6f56d-c4f8m Total loading time: 0 Render date: 2024-04-25T06:48:55.138Z Has data issue: false hasContentIssue false

Adsorption, Desorption, and Leaching of Nitrofen and Oxyfluorfen

Published online by Cambridge University Press:  12 June 2017

Omosuyi Fadayomi
Affiliation:
Dep. Hort.
G. F. Warren
Affiliation:
Dep. Hort.

Abstract

The adsorption of nitrofen (2,4-dichlorophenyl-p-nitrophenyl ether) and oxyfluorfen [2-cholor-1-(3-ethoxy-4-nitrophenoxy)-4-(trifluoromethyl)benzene] from aqueous solution by muck soil, and by kaolinite and bentonite saturated with hydrogen or calcium ions, was studied using 14C-labeled herbicides. Both compounds were readily adsorbed from solution by muck soil and Ca- and H-Al-bentonite but only slightly by Ca- and H-Al-kaolinite. Very little of the adsorbed compounds was desorbed after four extractions with distilled water. A bioactivity study using sorghum seedlings (Sorghum bicolor L. ‘RS610′) was conducted with the herbicides in a silica sand medium amended with 1% (w/w) of the various adsorbents. The herbicides were strongly inactivated by muck soil but there was very little inactivation by the clays. There was essentially no movement of either herbicide through 5-cm columns of a silt loam soil and a fine sand soil.

Type
Research Article
Copyright
Copyright © 1977 by the Weed Science Society of America 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Literature Cited

1. Ashton, F.M. and Crafts, A.S. 1973. Mode of action of herbicides. Pages 404406, 411–413. John Wiley and Sons. New York.Google Scholar
2. Bailey, G.W. and White, J.W. 1964. Review of adsorption and desorption of organic pesticides by soil colloids with implications concerning pesticide bioactivity. J. Agric. Food Chem. 12:324332.CrossRefGoogle Scholar
3. Bailey, G.W. and White, J.W. 1970. Factors affecting the adsorption, desorption and movement of pesticides in soils. Residue Rev. 32:2992.Google Scholar
4. Carlson, W.C., Lignowski, E.M., and Hopen, H.J. 1975. Uptake, translocation, and adsorption of pronamide. Weed Sci. 23:148154.CrossRefGoogle Scholar
5. Doherty, P.J. and Warren, G.F. 1969. The adsorption of four herbicides by different types of organic matter and bentonite clay. Weed Res. 9:2026.CrossRefGoogle Scholar
6. Grover, R. 1973. The adsorptive behavior of acid and ester forms of 2,4-D on soils. Weed Res. 13:5158.CrossRefGoogle Scholar
7. Grover, R. 1974. Absorption and desorption of trifluralin, triallate, and diallate by various adsorbents. Weed Sci. 22:405408.CrossRefGoogle Scholar
8. Harris, C.I. 1966. Adsorption, movement and phytotoxicity of monuron and s-triazines in soils. Weeds. 14:610.Google Scholar
9. Harris, C.I. and Sheets, T.J. 1965. Influence of soil properties on adsorption and phytotoxicity of CIPC, diuron and simazone. Weeds 13:215219.CrossRefGoogle Scholar
10. Harris, C.I. and Warren, G.F. 1964. Adsorption and desorption of herbicides by soil. Weeds 12:120126.Google Scholar
11. Harvey, R.G. 1974. Soil adsorption and volatility of dinitroaniline herbicides. Weed Sci. 22:120124.Google Scholar
12. Harward, M.E. and Coleman, N.T. 1954. Some properties of H-and Al-clays and exchange resins. Soils Sci. 78:181188.Google Scholar
13. Hayes, M.H.B. 1970. Adsorption of triazine herbicides on soil organic matter including a short review of organic matter chemistry. Residue Rev. 32:131174.Google Scholar
14. Nearpass, D.C. 1965. Effects of soil acidity on the adsorption, penetration and persistence of simzaine. Weeds 13:341346.CrossRefGoogle Scholar
15. Talbert, R.E. and Fletchall, O.H. 1965. The adsorption of some s-triazines in soils. Weeds 13:4652.CrossRefGoogle Scholar
16. Weber, J.B. 1972. Model soil systems, herbicide leaching and sorption. Pages 145160 in Wilkinson, R.E., ed. Research methods in weed science. South Weed Sci. Soc. POP Enterprises, Inc., Atlanta, Georgia and Creative Printers, Griffin, Georgia.Google Scholar
17. Yih, R.Y. and Swithenbank, Colin. 1975. New potent diphenyl ether herbicides. J. Agric. Food Chem. 23:592593.CrossRefGoogle ScholarPubMed