Hostname: page-component-8448b6f56d-c4f8m Total loading time: 0 Render date: 2024-04-24T02:57:46.345Z Has data issue: false hasContentIssue false

Optical and structural properties of ZnSxSe1−x thin films deposited by thermal evaporation

Published online by Cambridge University Press:  04 July 2009

M. Ashraf
Affiliation:
Optics Laboratories, P.O. Box 1021, Islamabad, Pakistan
S. M.J. Akhtar
Affiliation:
Optics Laboratories, P.O. Box 1021, Islamabad, Pakistan
M. Mehmood
Affiliation:
Pakistan Institute of Engineering and Applied Sciences, P.O. Nilore, Islamabad, Pakistan
A. Qayyum*
Affiliation:
Physics Division, Pakistan Institute of Nuclear Science and Technology, P.O. Nilore, Islamabad, Pakistan
Get access

Abstract

The ZnSxSe$_{1-x}$ (0 x 1) films were deposited on soda lime glass substrates by thermal evaporation technique. Optical and structural properties of these films were compared with the ZnSxSe$_{1-x}$ films deposited by various other techniques. XRD measurement showed that ZnSxSe$_{1-x}$ films are polycrystalline in nature with the preferred orientation along [111]. It was observed that the lattice constant decreases and the optical energy band gap increases with the sulfur content of the film. These results are in good agreement with the properties of ZnSxSe$_{1-x}$ films deposited by various other methods. Additionally, it was observed that the refractive index of a ZnSxSe$_{1-x}$ film decreases with increasing sulfur content. The results reported in this paper suggest that the lattice constants, optical energy band gap and refractive index of ZnSxSe$_{1-x}$ film can be tailored for a specific application by selecting suitable value of x.

Keywords

Type
Research Article
Copyright
© EDP Sciences, 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

D. Lincot, R. Ortega-Borges, J. Vedel, M. Ruckh, J. Kesler, K.O. Velthaus, D. Harriskos, H.W. Schock, in Proc. 11th European Photovoltaic Solar Energy Conference, Montreux, 1992, edited by L. Guimaraes, W. Palz, C. De Reyff, H. Kiess, P. Helm (Harwood Academic Publisher, 1992), p. 870
Contreras, M.A., Ramanathan, K., Abushama, J., Hasoon, F., Young, D.L., Egaas, B., Noufi, R., Prog. Photovolt. Res. Appl. 13, 209 (2005) CrossRef
C. Ferekids, S. Marinskaya, D. Marinskiy, V. Palekis, D.L.S. Morel, in Proc. 2nd World Conf. and Exhibition on Photovoltaic Solar Energy Conversion, Vienna, 1998 (European Commission Joint Research Centre, 1998), p. 1085
R. Dhere, X. Wu, D. Albin, C. Perkins, H. Moutinho, T. Gessert, in Proc. 29th IEEE Photovoltaic Specialists Conference, New Orleans, LA, 2002, p. 484
Gaines, J.M., Drenten, R.R., Haberen, K.W., Marshall, T., Mensz, P., Petruzzello, J., Appl. Phys. Lett. 62, 2462 (1993) CrossRef
Miura, N., Ogawa, K., Kobayashi, S., Matsumoto, H., Nakano, R., J. Cryst. Growth 138, 1046 (1994) CrossRef
Fujiwara, H., Kiryu, H., Shimizu, I., J. Appl. Phys. 77, 3927 (1995) CrossRef
Brownlie, G.D., Vogele, B., Meredith, W., Milnes, J.S., Prior, K.A., Cavenett, B.C., J. Cryst. Growth 184-185, 37 (1999) CrossRef
Mitsuishi, I., Mitsuhashi, H., Kukimoto, H., Jpn J. Appl. Phys. 28, L275 (1989) CrossRef
Armstrong, S., Datta, P.K., Miles, R.W., Thin Solid Films 403-404, 126 (2002) CrossRef
Gordillo, G., Romero, E., Thin Solid Films 484, 352 (2005) CrossRef
Pashinkin, A.S., Tishchenko, G.N., Korneeva, I.V., Ryzhenko, B.B., Sov. Phys. Crystallogr. 6, 243 (1960)
J. Tauc (Ed.) Amorphous and Liquid Semiconductors (Plenum, New York, 1974), p. 159
Ihanus, J., Ritala, M., Leskelä, M., Rauhala, E., Appl. Surf. Sci. 112, 154 (1997) CrossRef
Kumar, V., Sharma, T.P., Opt. Mater. 10, 253 (1998) CrossRef
Swanepoel, R.J., J. Phys. E: Sci. Instrum. 16, 1214 (1983) CrossRef
Swanepoel, R.J., J. Phys. E: Sci. Instrum. 17, 896 (1984) CrossRef
Aqili, A.K.S., Maqsood, A., Ali, Z., Appl. Surf. Sci. 191, 280 (2002) CrossRef
Pal, R., Chaudhuri, S., Pal, A.K., Vacuum 46, 1255 (1995) CrossRef
Ali, Z., Aqili, A.K.S., Maqsood, A., Akhtar, S.M.J., Vacuum 80, 302 (2005) CrossRef