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Nickel concentration dependent structural and optical properties of electrodeposited diamond like carbon thin films

  • Beauty Pandey (a1), Jonaki Mukherjee (a1), Bidyut Das (a1) and Asit K. Kar (a1)

Abstract

Diamond like carbon (DLC) and composite nickel incorporated diamond-like carbon (Ni-DLC) films have been synthesized on ITO coated glass substrates using low voltage electrodeposition method. Modifications of structural and optical properties of thin films have been investigated with varying Ni concentration. Average grain size of Ni-DLC granules is found to decrease with increasing molarity of Ni in electrolytic solution. XRD pattern depicts multi-phase nature of Ni-DLC film. Incorporation of Ni nanoparticles in DLC matrix has been confirmed by TEM. Interestingly optical bandgap energy decreases from 2.31 to 1.58 eV with decrease in nickel content in the electrolytic bath. Simultaneously Urbach energy exhibits an increasing trend from 1.972 to 2.374 eV. Presence of sp2 and sp3 bonded carbons has been indicated by FTIR spectra. The number of sp2 bonding in carbon matrix is enhanced with dilution of electrolyte. The peaks in the range of ~600–750 cm−1 in Ni-DLC films have been attributed to metal incorporation into DLC matrix. Study reveals that the bandgap and the particle size of carbon nanocomposite films can be tailored by controlling the amount of nickel in the electrolyte.

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[1] Robertson, J., Mater. Sci. Eng. R 37, 129 (2002)
[2] Kayani, A.N., Ph.D. thesis, Ohio University, 2003
[3] Angus, J.C., Koidl, P., Domitz, S., in Plasma Deposited Thin Films , edited by Mort, J., Jansen, F. (CRC Press Boca Raton, Florida, 1986)
[4] Voevodin, A.A., Zabinski, J.S., Thin Solid Films 268, 223 (2000)
[5] Voevodin, A.A., Walck, S.D., Zabinski, J.S., Wear 203–204, 516 (1997)
[6] Yokota, K., Nakatani, T., Miyashita, F., Eur. Phys. J. Appl. Phys. 39, 17 (2007)
[7] Paul, R., Dalui, S., Das, S.N., Bhar, R., Pal, A.K., Appl. Surf. Sci. 255, 1705 (2008)
[8] Vandevelde, T.C.S., Vandierendonck, K., Van Stappen, M., Du Mong, W., Perremans, P., Surf. Coat. Technol. 113, 80 (1999)
[9] Chu, P.K., Li, L., Mater. Chem. Phys. 96, 253 (2006)
[10] Gupta, S., Chowdhury, M.P., Pal, A.K., Appl. Surf. Sci. 236, 426 (2004)
[11] Robertson, J., Surf. Coat. Technol. 50, 185 (1992)
[12] Suzuki, T., Manita, Y., Yamazaki, T., Wada, S., Noma, T., J. Mater. Sci. 30, 2067 (1995)
[13] Wang, H., Shen, M., Ning, Z., Ye, C., Cao, C., Dang, H., Zhu, H., Appl. Phys. Lett. 69, 1074 (1996)
[14] Roy, R., Deb, B., Bhattacharjee, B., Pal, A.K., Thin Solid Films 422, 92 (2002)
[15] Schwartz, M., in Handbook of Deposition Technologies for Films and Coatings – Science, Technology and Applications , edited by Bunshah, R.F. 2nd edn (William Andrew Publishing, New Jersey, 1994), pp. 506616
[16] Namba, Y., J. Vac. Sci. Technol. A 10, 3368 (1992)
[17] Cao, C., Zhu, H., Wang, H., Thin Solid Films 368, 203 (2000)
[18] Meng, W.J., Gillispie, B.A., J. Appl. Phys. 84, 4314 (1998)
[19] Hauert, R., Glisenti, A., Metin, S., Goitia, J., Kaufman, J.H., Thin Solid Films 268, 22 (1995)
[20] Paul, R., Gayen, R.N., Hussain, S., Khanna, V., Bhar, R., Pal, A.K., Eur. Phys. J. Appl. Phys. 47, 10502 (2009)
[21] Krishna, K.M., Soga, T., Mukhopadhyay, K., Sharon, M., Umeno, M., Sol. Energy Mater. Sol. Cells 48, 25 (1997)
[22] Lazar, G., Lazar, I., J. Non-Cryst. Solids 331, 70 (2003)
[23] Adhikary, S., Tian, X.M., Adhikari, S., Omer, A.M.M., Uchida, H., Umeno, M., Diamond Rel. Mater. 14, 1832 (2005)
[24] Dimigen, H., Hubsch, H., Memming, R., Appl. Phys. Lett. 50, 1056 (1987)
[25] Grill, A., Patel, V., Cohen, S.A., Diamond Rel. Mater. 3, 281 (1994)
[26] Lau, S.P., Li, Y.J., Tay, B.K., Sun, Z., Chen, G.Y., Ding, X.Z., Diamond Rel. Mater. 10, 1727 (2001)
[27] Hussain, S., Pal, A.K., Appl. Surf. Sci. 253, 3649 (2007)
[28] Hussain, S., Roy, R.K., Pal, A.K., J. Phys. D: Appl. Phys. 38, 900 (2005)
[29] Chen, J.S., Lau, S.P., Chen, G.Y., Sun, Z., Li, Y.J., Tay, B.K., Chai, J.W., Diamond Rel. Mater. 10, 2018 (2001)
[30] Pasaja, N., Sansongsiri, S., Intarasiri, S., Vilaithong, T., Anders, A., Nucl. Instr. Methods Phys. Res. B 259, 867 (2007)
[31] Koh, A.T.T., Hsieh, J., Chua, D.H.C., Diamond Rel. Mater. 19, 637 (2010)
[32] Ma, K., Yang, G., Yu, L., Zhang, P., Surf. Coat. Technol. 204, 2546 (2010)
[33] Khun, N.W., Liu, E., Yang, G.C., Surf. Coat. Technol. 204, 3125 (2010)
[34] Wan, S., Yu, Y., Zhang, J., Wang, L., Appl. Surf. Sci. 256, 4873 (2010)
[35] Pandey, B., Hussain, S., J. Phys. Chem. Solids 72, 1111 (2011)
[36] Pandey, B., Pal, P.P., Bera, S., Ray, S.K., Kar, A.K., Appl. Surf. Sci. 261, 789 (2012)
[37] Pal, P.P., M.Phil Dissertation, I.S.M. Dhanbad, 2010
[38] Schiffmann, K.I., Fryda, M., Goerigk, G., Lauer, R., Hinze, P., Bulack, A., Thin Solid Films 347, 60 (1999)
[39] Anton, R., Carbon 46, 656 (2008)
[40] Marsh, H., Warburton, A.P., J. Appl. Chem. 20, 133 (1970)
[41] Lamber, R., Jaeger, N., Ekloff, G.S., Surf. Sci. 197, 402 (1988)
[42] Takeno, T., Hoshi, Y., Miki, H., Takagi, T., Diamond Rel. Mater. 17, 1669 (2008)
[43] Tamor, M.A., Vassell, W.C., Karduner, K.R., Appl. Phys. Lett. 58, 592 (1991)
[44] Thorpe, M.F., J. Non-Cryst. Solids 57, 355 (1983)
[45] Robertson, J., O’Reilly, E.P., Phys. Rev. B 35, 2946 (1987)
[46] Robertson, J., Diamond Rel. Mater. 2, 984 (1993)
[47] Mukherjee, J., M.Sc Dissertation, I.S.M. Dhanbad, 2010
[48] Manifacier, J.C., Murcia, M., Fillard, J.P., Vicario, E., Thin Solid Films 41, 127 (1977)
[49] Savvides, N., J. Appl. Phys. 59, 4133 (1986)
[50] Bhattacharyya, D., Chaudhuri, S., Pal, A.K., Vacuum 43, 313 (1992)
[51] Fourches, N., Turban, G., Thin Solid Films 240, 28 (1994)
[52] Kreibig, U., Genzel, L., Surf. Sci. 156, 687 (1985)
[53] Hilger, A., Cuppers, N., Tenfelde, N., Kreibig, U., Eur. Phys. J. D 10, 115 (2000)
[54] Pinchuk, A., Kreibig, U., New J. Phys. 5, 151 (2003)
[55] Jungnickel, G., Frauenheim, T., Proezag, D., Blaudeck, P., Stephen, U., Phys. Rev. B 50, 6709 (1994)
[56] Chen, C.W., Robertson, J., J. Non-Cryst. Solids 227/228, 602 (1998)
[57] McCulloch, D.G., McKenzie, D.R., Goringe, C.M., Phys. Rev. B 61, 2349 (2000)
[58] Shin, J.H., van den Hoven, G.N., Polman, A., Appl. Phys. Lett. 66, 2379 (1995)
[59] Lee, S., Kim, D.S., Rhee, S.G., Oh, S.G., Lee, K.R., Thin Solid Films 341, 68 (1999)
[60] Kumar, S., Dixit, P.N., Panwar, O.S., Bhattacharyya, R., Diamond Rel. Mater. 12, 1576 (2003)
[61] Cody, G.D., J. Non-Cryst. Solids 141, 3 (1992)
[62] O’Leary, S.K., Appl. Phys. Lett. 72, 1332 (1998)
[63] Shi, X., Leah, L.K., Tay, B.K., Thin Solid Films 312, 166 (1998)
[64] Hayashi, Y., Yu, G., Rahman, M.M., Krishna, K.M., Soga, T., Jimbo, T., Umeno, M., J. Appl. Phys. 89, 7924 (2001)
[65] Deraman, K., Sarmid, S., Ismail, B., Ahmad, N.E., Hussin, R., Nurulhuda, W., Shamsuri, W., Nor, M., Yusof, M., Hamzah, K., J. Fundam. Sci. 7, 1 (2011)
[66] Ristein, J., Stief, R.T., Ley, L., Beyer, W., J. Appl. Phys. 84, 3836 (1998)
[67] Das, B., M.Sc Dissertation, I.S.M. Dhanbad, 2010
[68] McNamara, K.M., Williams, B.E., Glenson, K.K., Sproggs, B.E., J. Appl. Phys. 76, 2466 (1994)
[69] Chou, L.H., Wang, H.W., J. Appl. Phys. 74, 4673 (1993)
[70] Dyer, J.R., Applications of Absorption Spectroscopy of Organic Compounds (Prentice-Hall of India, New Delhi, 2002)
[71] Sharma, Y.R., Elementary Organic Spectroscopy (S. Chand & Co, New Delhi, 2003)
[72] Dischler, B., Bubenzer, A., Koidl, P., Appl. Phys. Lett. 42, 636 (1983)
[73] Gang, W., Yuedong, M., Shaofeng, Z., Feng, L., Zhongqing, J., Plasma Sci. Technol. 10, 78 (2008)
[74] Mawhinney, D.B., Naumenko, V., Kuznetsova, A., Yates, J.T. Jr., Liu, J., Smalley, R.E., J. Am. Chem. Soc. 122, 2383 (2000)
[75] Omer, A.M.M., Adhikari, S., Adhikary, S., Rusop, M., Uchida, H., Soga, T., Umeno, M., Diamond Rel. Mater. 15, 645 (2006)

Nickel concentration dependent structural and optical properties of electrodeposited diamond like carbon thin films

  • Beauty Pandey (a1), Jonaki Mukherjee (a1), Bidyut Das (a1) and Asit K. Kar (a1)

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