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Calorimetric studies of chalcogenide glasses in the system Se-S

Published online by Cambridge University Press:  15 March 2001

O. El-Shazly*
Affiliation:
Department of Physics, Faculty of Science, United Arab Emirates University, PO Box 17551, Al-Ain, United Arab Emirates
T. Ramadan
Affiliation:
Institute of Graduate Studies and Research, Alexandria University, Alexandria, Egypt
N. El-Anany
Affiliation:
Department of Physics and Chemistry, Faculty of Education, Damanhour, Alexandria University, Egypt
H. A. Motaweh
Affiliation:
Department of Physics and Chemistry, Faculty of Education, Damanhour, Alexandria University, Egypt
E. F. El-Wahidy
Affiliation:
Department of Physics, Faculty of Science, Alexandria University, Alexandria, Egypt
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Abstract

Differential scanning calorimetry measurements under non-isothermal conditions were performed on the chalcogenide glasses Se98−x Sx Sn2 (x = 8, 18) and Se77 S20 X3 (X = Sn, Pb). The values of the glass transition temperature and crystallization temperature were found to depend on the heating rate. The activation energy for the glass transition and the activation energy for crystallization were calculated from the heating rate-dependence. The thermal stability and the glass forming tendency were calculated and they were found to have the same trend.

Keywords

Type
Research Article
Copyright
© EDP Sciences, 2001

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