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Yttrium implantation and addition element effects on high temperatureoxidation behaviour of reference steels

Published online by Cambridge University Press:  15 February 2002


E. Caudron
Affiliation:
Laboratoire Vellave d'Élaboration et d'Étude des Matériaux, Équipe Locale Université Blaise Pascal de Clermont-Ferrand II, Institut Universitaire de Technologie, Département de Chimie-Sciences des Matériaux, BP 219, 43006 Le Puy en Velay, France
F. Riffard
Affiliation:
Laboratoire Vellave d'Élaboration et d'Étude des Matériaux, Équipe Locale Université Blaise Pascal de Clermont-Ferrand II, Institut Universitaire de Technologie, Département de Chimie-Sciences des Matériaux, BP 219, 43006 Le Puy en Velay, France
H. Buscail
Affiliation:
Laboratoire Vellave d'Élaboration et d'Étude des Matériaux, Équipe Locale Université Blaise Pascal de Clermont-Ferrand II, Institut Universitaire de Technologie, Département de Chimie-Sciences des Matériaux, BP 219, 43006 Le Puy en Velay, France
R. Cueff
Affiliation:
Laboratoire Vellave d'Élaboration et d'Étude des Matériaux, Équipe Locale Université Blaise Pascal de Clermont-Ferrand II, Institut Universitaire de Technologie, Département de Chimie-Sciences des Matériaux, BP 219, 43006 Le Puy en Velay, France
C. Issartel
Affiliation:
Laboratoire Vellave d'Élaboration et d'Étude des Matériaux, Équipe Locale Université Blaise Pascal de Clermont-Ferrand II, Institut Universitaire de Technologie, Département de Chimie-Sciences des Matériaux, BP 219, 43006 Le Puy en Velay, France
S. Perrier
Affiliation:
Laboratoire Vellave d'Élaboration et d'Étude des Matériaux, Équipe Locale Université Blaise Pascal de Clermont-Ferrand II, Institut Universitaire de Technologie, Département de Chimie-Sciences des Matériaux, BP 219, 43006 Le Puy en Velay, France
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Abstract

Yttrium implanted and unimplanted various reference steels were oxidized at 700 °C, under controlled atmosphere (oxygen partial pressure: 0.04 Pa), for 24 h to observe the yttrium implantation and the addition element effects on steel high temperature oxidation behaviours. Yttrium implantation effects on reference steels were characterized using analytical and structural techniques such as Rutherford Backscattering Spectrometry (RBS), Reflection High Energy Electron Diffraction (RHEED), X-ray Diffraction (XRD) and Glancing Angle X-ray Diffraction (GAXRD). Yttrium implanted and unimplanted reference steel oxidation behaviours were observed by thermogravimetry and in situ high temperature X-ray diffraction. Our results clearly show that yttrium implantation and high temperature oxidation induced the formation of several yttrium mixed oxides which closely depend on the reference steel addition elements. Moreover, these yttrium mixed oxides seem to be responsible for the improved reference steel oxidation resistance at high temperature.


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Type
Research Article
Copyright
© EDP Sciences, 2002

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