Hostname: page-component-76fb5796d-dfsvx Total loading time: 0 Render date: 2024-04-27T02:54:00.040Z Has data issue: false hasContentIssue false

A Possible Source of Error in 14C Dates: Volcanic Emanations (Examples from the Monte Amiata District, Provinces of Grosseto and Sienna, Italy)

Published online by Cambridge University Press:  18 July 2016

Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Wood from regular timbering of a shallow seated mine in Tuscany gave 14C ages of 5730 ± 100 years BP, much too old to be attributed to one of the known civilizations of Italy. This mine is located in a region of declining volcanic activity, noticeable especially through numerous emanations (natural or incidentally induced by drillings). It was suspected that the analyzed wood had grown in an environment where the normal atmosphere had been diluted by volcanic emanations. To check this hypothesis, living plants (trees, bushes and reeds) and volcanic emanations have been sampled and their 14C content measured. All present day plants are depleted in 14C, giving a fictitious age different from 0 (1805, 1820, 2540, 4350 years BP). Of the gaseous emanations sampled, two have a high pressure and show virtually no 14C (>41,000 years BP). Two others have a pressure close to atmospheric, and small amounts of 14C were introduced by atmospheric contamination (22,570 and 30,580 years BP).

Conclusion: plants grown in the vicinity of volcanic emanations have 14C activities that are too low because of a natural 14C dilution and yield anomalously high ages. The δ13C values obtained for two of these plants (—27.4‰ and —23.7‰) are close to the average for plants in general (—25‰), whereas the CO2 of mofettes is heavier than atmospheric CO2.

Type
Dating Various Materials
Copyright
Copyright © The American Journal of Science 

References

Calamai, A, Cataldi, R, Squarci, P, and Taffi, L, 1970, Geology, geophysics and hydrogeology of the Monte Amiata geothermal fields: Geothermics, Spec issue, v 1, 8 p.Google Scholar
Cataldi, R, 1967, Remarks on the geothermal research in the region of Monte Amiata (Tuscany-Italy): Bull Volcanol, v 30, p 243269.CrossRefGoogle Scholar
Chatters, R M, Crosby, J W, and Engstrand, L G, 1969, Fumarole gaseous emanations: their influence on carbon-14 dates: Washington State Univ, Coll Eng, circ 32, 9 p.Google Scholar
Evernden, J F and Curtis, G H, 1965, The potassium-argon dating of Late Cenozoic rocks in East Africa and Italy: Current Anthropol, v 6, p. 343-385.Google Scholar
Friedman, I and O'Neil, J R, 1977, Compilation of stable isotope fractionation factors of geochemical interest, in Fleischer, M, ed, Data of geochemistry, 6th ed: US Geol Survey Prof Paper 440, 12 p.Google Scholar
Hassko, Bertalan, Guillet, Bernard, Jaegy, Robert, and Coppens, René, 1974, Nancy natural radiocarbon measurements III: Radiocarbon, v 16, p 118130.Google Scholar
Haupt, Theodor, 1889, Il rendiconto del mio stato de servizio: Firenze, Le Monnier.Google Scholar
Keeling, C D, Mook, W G, and Tans, P P, 1979, Recent trends in the 13C/12C ratio of atmospheric carbon dioxide: Nature, v 277, p 121123.Google Scholar
Mazzuoli, R, and Pratesi, M, 1963, Rilevamento e studio chimico-petrografico delle rocche vulcaniche del Monte Amiata: Soc Toscana Sci naturale Atti, ser A, v 70, p 355429.Google Scholar
Panichi, Costanzo and Tongiorgi, Ezio, 1975, Carbon isotopic composition of CO2 from springs, fumaroles, mofettes, and travertines of Central and Southern Italy: a preliminary prospection method of geothermal area: UN symposium on development and use of geothermal resources, 2nd, Proc: San Francisco, Lawrence Berkeley Lab, Univ California.Google Scholar
Paul, E A, and Van Veen, S A, 1978, The use of tracers to determine the dynamic nature of organic matter, Internatl conf on soil sci, Proc: Edmonton, Canada, v 1, p 61102.Google Scholar
Pellizer, Renato, ed, 1971, La Toscana meridionale: Soc Mineralog e Petrolog italiana Rend, v 27, (fasc spec), 571 p.Google Scholar
Scharpenseel, H W, and Pietig, F, 1969, Einfache Boden- und Wasserdatierung durch Messung der 14C- oder Tritiumkonzentration: Geoderma, v 2, p 273289.Google Scholar
Smith, B N and Epstein, Samuel, 1971, Two categories of 13C/12C ratios for higher plants: Plant Physiology, v 47, p 380384.Google Scholar
Squarzina, Federico, 1965, Italia Mineraria: Assoc Min Italiana, 742 p.Google Scholar
Strappa, Osvaldo, 1977, Storia delle miniere di mercurio del Monte Amiata: Industria Min, v 28, nos. 4-6, 27 p.Google Scholar