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XI.—Further Tests upon Dewar Flasks intended to hold Liquid Air

Published online by Cambridge University Press:  15 September 2014

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Extract

This communication describes a series of experiments carried out at the Heriot-Watt College, Edinburgh, on behalf of the Oxygen Research Committee, Scientific and Industrial Research Department. The experiments may be regarded as continuing a line of inquiry introduced by a paper read before the Society in 1921; their aim was to obtain data in regard to the rate of decay of the vacua (i.e. the rate of increase of the pressure in the vacuum envelope) of metallic Dewar vessels.

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Proceedings
Copyright
Copyright © Royal Society of Edinburgh 1924

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References

page 160 note * An Experimental Analysis of the Losses by Evaporation of Liquid Air contained in Vacuum Flasks,” by Briggs, H., Proc. R.S.E., xli, p. 97.Google Scholar

page 160 note † Ibid., pp. 98, 99.

page 160 note ‡ Ibid., p. 107.

page 161 note * The manner of construction of the vessels, the selection of suitable metal and solder, the process of testing prior to evacuation, and the method of evacuation are dealt with in detail in the forthcoming Report of the Oxygen Research Committee.

page 167 note * The pressure-reduction factor (i.e. the relation between the pressure in a given space before and after the charcoal is brought into action by being cooled to liquid-air temperature) is discussed in a paper (“Prehensility: a Factor of Gaseous Adsorption,” Proc., xlii, 1921–2, p. 26) which one of us read to the Society in 1921. The method of investigation, then pursued, depended on an experimental observation of Dewar, supported by the theoretical results of Williams, to the effect that the adsorption isotherm is virtually a straight line near the origin. Our own observations, set forth in that paper, bear out that view, but experiments now being conducted at Oxford on behalf of the Oxygen Research Committee point to the probability of a departure from the linear relationship in the isotherm at extremely low pressures. The matter receives attention in the forthcoming Report of that Committee. It therefore seems not unlikely that, with the order of pressure obtaining in Dewar flasks, the pressure-reduction factor will prove to be much greater than the one (namely, 1000) assumed in this argument. From the present point of view, the only effect of such a change would be to emphasise considerably our conclusions as to the relative importance of the radiation and conduction loss of these flasks and in regard to the needlessness of very fine evacuation by pumping. Evidence of a high pressure-reduction factor is provided by the results obtained with container No. 12.