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On the Application of Van der Waals' Equation to the Compression of Ordinary Liquids

Published online by Cambridge University Press:  15 September 2014

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Extract

In a paper, read for me to the Society in January last (ante, p. 245), I pointed out the difficulties I had met with in trying to reconcile Van der Waals' equation with Amagat's experimental data for common liquids, and I promised to recur to the question when the state of my health should permit. I now find that, as I had then only surmised, the constants in Van der Waals' equation necessarily become non-real when we try to adjust it to Amagat's data.

Type
Proceedings
Copyright
Copyright © Royal Society of Edinburgh 1895

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