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X-ray powder diffraction data for Copper (II). bis[(2E)-3-methoxy-2- [(2,4,6-trimethylphenyl)imino]-4-[(2,4,6-trimethylphenyl)imino-κN]- 3-pentanolato-κO] complex

  • R. Pažout (a1), J. Maixner (a1), A. Sokolohorskyj (a2) and J. Merna (a2)

Abstract

X-ray powder diffraction data, unit-cell parameters and space group for a new bis(β-diiminato) Cu(II) complex, C48H62CuN4O4 are reported [a = 13.330 (3) Å, b = 11.137(2) Å, c = 8.832(2) Å, α = 78.88(2), β = 94.73(2), γ = 114.55(2), unit-cell volume V = 1170.26 Å3, Z = 1, and space group P − 1]. All measured lines were indexed and are consistent with the P−1 space group. No detectable impurity was observed.

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a) Author to whom correspondence should be addressed. Electronic mail: richard.pazout@vscht.cz

References

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Asay, M., Jones, C., and Driess, M. (2011). “N-Heterocyclic carbene analogues with low-valent Group 13 and Group 14 elements: syntheses, structures, and reactivities of a new generation of multitalented ligands,” Chem. Rev. 111, 354396.
Boultif, A. and Louër, D. (2004). “Powder pattern indexing with the dichotomy method,” J. Appl. Crystallogr. 37, 724731.
Bourget-Merle, L., Lappert, M. F., and Severn, J. R. (2002). “The chemistry of beta-diketiminatometal complexes,” Chem. Rev. 102, 30313065.
De Wolff, P. M. (1968). “A simplified criterion for the reliability of a powder pattern indexing,” J. Appl. Crystallogr. 1, 108113.
Feldman, J., McLain, S. J., Parthasarathy, A., Marshall, W. J., Calabrese, J. C., and Arthur, S. D. (1997). “Electrophilic metal precursors and a beta-diimine ligand for nickel(II)- and palladium(II)-catalyzed ethylene polymerizations,” Organometallics 16, 15141516.
Smith, G. S. and Snyder, R. L. (1979). “FN: a criterion for rating powder diffraction patterns and evaluating the reliability of powder indexing,” J. Appl. Crystallogr. 12, 6065.
Yokota, S., Tachi, Y., and Itoh, S. (2002). “Oxidative degradation of β-diketiminate ligand in copper(II) and zinc(II) complexes,” Inorg. Chem. 41, 13421344.

Keywords

X-ray powder diffraction data for Copper (II). bis[(2E)-3-methoxy-2- [(2,4,6-trimethylphenyl)imino]-4-[(2,4,6-trimethylphenyl)imino-κN]- 3-pentanolato-κO] complex

  • R. Pažout (a1), J. Maixner (a1), A. Sokolohorskyj (a2) and J. Merna (a2)

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