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Structure determination of a novel metal-organic compound synthesized from aluminum and 2,5-pyridinedicarboxylic acid

Published online by Cambridge University Press:  06 March 2012

Kenny Ståhl ,
Bastian Brink  and
Jonas Andersen
Kenny Ståhl*
Affiliation:
Department of Chemistry, Building 207, Technical University of Denmark, DK-2800 Kgs. Lyngby, Denmark
Bastian Brink
Affiliation:
Department of Chemistry, Building 207, Technical University of Denmark, DK-2800 Kgs. Lyngby, Denmark
Jonas Andersen
Affiliation:
Department of Chemistry, Building 207, Technical University of Denmark, DK-2800 Kgs. Lyngby, Denmark
*
a)Author to whom correspondence should be addressed. Electronic mail: kenny@kemi.dtu.dk
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Abstract

The structure of [Al2(pydc)2(μ2-OH)2(H2O)2]n(pydc = 2,5-pyridinedicarboxylate) was successfully determined from powder X-ray diffraction data. The compound crystallizes in the triclinic system (space group P -1) with a = 6.7813(1) Å, b = 7.4944(1) Å, c = 8.5013(1) Å, α = 95.256(1)°, β = 102.478(1)°, γ = 108.979(1)°. The structure consists of aluminum ions coordinating N and O in distorted octahedra, sharing an edge through two hydroxide ions. These dinuclear complexes are connected by pydc ions, which at one end coordinate by nitrogen and oxygen and only by oxygen at the other end. The pydc orientation is reversed in the neighboring pydc, forming double stranded chains interconnected by the aluminum dinuclear complexes in a ladder-like arrangement along [001].

Keywords

aluminum2,5-pyridinedicarboxylic acidhydrothermal synthesismetal-organic frameworkXRPD
Type
Technical Articles
Information
Powder Diffraction , Volume 26 , Supplement S1 , December 2011 , pp. S44 - S46
Copyright
Copyright © Cambridge University Press 2011

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