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Powder diffraction data of novel complexes CdX2-2(NH2-PhY), part I

Published online by Cambridge University Press:  29 February 2012

Anna Dobija
Affiliation:
Institute of Catalysis and Surface Chemistry, PAS, ul. Niezapominajek 8, 30-239 Krakow, Poland
Alicja Rafalska-Łasocha
Affiliation:
Faculty of Chemistry, Jagiellonian University, ul. Ingardena 3, 30-060 Krakow, Poland
Wiesław Łasocha*
Affiliation:
Institute of Catalysis and Surface Chemistry, PAS, ul. Niezapominajek 8, 30-239 Krakow, Polandand Faculty of Chemistry, Jagiellonian University, ul. Ingardena 3, 30-060 Krakow, Poland
*
a)Author to whom correspondence should be addressed; Electronic mail: lasocha@chemia.uj.edu.pl

Abstract

Four new compounds with general formula CdI2-2(NH2-PhX) (Ph represents phenyl radical; X represents Cl or H atoms) were obtained and characterized. Two of them, bisaniline diiodidecadmium(II) — CdI2⋅2[NH2–C6H5] {1} and bis(2-chloroaniline) diiodidecadmium(II) — CdI2⋅2[NH2–C6H4Cl] {2}, crystallize in monoclinic system, whereas another two, bis(3-chloroaniline) diiodidecadmium(II) — CdI2⋅2[NH2–C6H4Cl]{3} and bis(4-chloroaniline) diiodidecadmium(II) hemi(4-chloroanilate) — CdI2⋅2[NH2–C6H4Cl]½[NH2–C6H4Cl] {4}, crystallize in triclinic system. The investigated compounds, from chemical point of view, are similar to the so-called cisplatin—a compound used as a chemotherapy drug to treat many types of cancers. Their syntheses and results of X-ray powder diffraction studies at room and elevated temperatures are described in this paper.

Type
New Diffraction Data
Copyright
Copyright © Cambridge University Press 2010

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References

Baldovino-Pantaleón, O., Morales-Morales, D., Hernández-Ortega, S., Toscano, R. A., and Valdés-Martinez, J. (2007). “Pd–N–H⋯Cl–Pd hydrogen bonds and π-π interactions between fluorinated aromatic rings in t r a n s-[PdCl2(NH2ArF)2],” Cryst. Growth Des. CGDEFU 7, 117123.10.1021/cg0606388CrossRefGoogle Scholar
de Wolff, P. M. (1968). “A simplified criterion for the reliability of a powder pattern indexing,” J. Appl. Crystallogr. JACGAR 1, 108113.10.1107/S002188986800508XCrossRefGoogle Scholar
Dobija, A., Nitek, W., and Łasocha, W., in press.Google Scholar
ICDD (2009). “Powder Diffraction File,” edited by Kabekkodu, S., International Centre for Diffraction Data, Newtown Square, Pennsylvania.Google Scholar
Łasocha, W. and Lewiński, K. (1994). “proszki—A system of programs for powder diffraction data analysis,” J. Appl. Crystallogr. JACGAR 27, 437438.CrossRefGoogle Scholar
Rademeyer, M. (2004). “Dianilinediiodozinc(II),” Acta Crystallogr., Sect. E: Struct. Rep. Online ACSEBH 60, m871–m872.10.1107/S160053680401181XCrossRefGoogle Scholar
Smith, G. S. and Snyder, R. L. (1979). “FN: A criterion for rating powder diffraction patterns and evaluating the reliability of powder-pattern indexing,” J. Appl. Crystallogr. JACGAR 12, 6065.10.1107/S002188987901178XCrossRefGoogle Scholar
Sonneveld, E. J. and Visser, J. W. (1975). “Automatic collection of powder data from photographs,” J. Appl. Crystallogr. JACGAR 8, 1–7.10.1107/S0021889875009417CrossRefGoogle Scholar
Thorn, A., Willet, R. D., and Twamley, B. (2006). “Novel series of ribbon structures in dialkylammonium chlorocadmates obtained by dimensional reduction of the hexagonal CdCl2 lattice,” Cryst. Growth Des. CGDEFU 6, 11341142.10.1021/cg050584mCrossRefGoogle Scholar