Hostname: page-component-7c8c6479df-hgkh8 Total loading time: 0 Render date: 2024-03-28T13:18:30.727Z Has data issue: false hasContentIssue false

Crystal structure of the three-dimensional magnetic network of type Mek[Fe(CN)6]l·mH2O, where Me=Cu, Ni, Co

Published online by Cambridge University Press:  10 January 2013

A. Ratuszna
Affiliation:
Institute of Physics, University of Silesia, Pl-40007 Katowice, Poland
S. Juszczyka*
Affiliation:
Institute of Physics, University of Silesia, Pl-40007 Katowice, Poland
G. Małecki
Affiliation:
Institute of Chemistry, University of Silesia, Pl-40006 Katowice, Poland

Abstract

The crystal structures of Mek[Fe(CN)6];l·mH2O where Me = Cu, Ni and Co, have been refined from X-ray (CuKa) powder diffraction data by means of Rietveld analyses in space group . The Fe and Me ions are octahedrally coordinated by C and N atoms respectively, forming three-dimensional bimetallic networks with the CN-groups as bridging ligands. The Me(l) sites (k = 2, l=1) and the Fe sites (k = 3, l = 2) are partially occupied. Water oxygens were placed in alternative, empty metal sites.

Type
Research Article
Copyright
Copyright © Cambridge University Press 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Allemand, P.M., Khemani, K.C., Koch, A., Wudl, F., Holczer, K., Donovan, S., Grüner, G., and Thompson, J.D. (1991). Molecular Magnetic Materials (Kluwer, Dordrecht), NATO ASI Series, Series E, Vol. 198, pp. 215232;Google Scholar
Science 253, 301304.CrossRefGoogle Scholar
Beall, G.W., Milligan, W.O., Korp, J., and Bernal, I. (1977), Inorg. Chem. 16, 27152718.Google Scholar
Bielański, A., (1973). General and Inorganic Chemistry (Polish Scientific, Warsaw) (in Polish).Google Scholar
Buser, H.J., Schwarzenbach, D., Petter, W., and Ludi, A. (1977). Inorg. Chem. 16, 27042710.Google Scholar
Caglioti, G., Paleotti, A., and Ricci, F.P. (1958). Nucl. Instrum. 3, 223228.Google Scholar
Caneshi, A. (1991). Molecular Magnetic Materials (Kluwer, Dordrecht), NATO ASI Series, Series E, Vol. 198, pp. 215232.Google Scholar
Gadet, V., Mallah, I., Castro, I., Verdaguer, M., and Veillet, P. (1992). J. Am. Chem. Soc. 114, 92139214.Google Scholar
Griebler, W. and Babel, D. (1982). Z. Naturforsch. 37b, 832837.Google Scholar
Juszczyk, S., Johansson, C., Hanson, M., Ratuszna, A., and Malecki, G. (1994a). J. Phys. Condensed Matter 6, 56975706.Google Scholar
Juszczyk, S., Johansson, C., Hanson, M., Ratuszna, A., and Malecki, G. (1994b). J. Magn. Magn. Mater. 138, 281286.Google Scholar
Kahn, O. (1991). Molecular Magnetic Materials (Kluwer, Dordrecht), NATO ASI Series, Series E, Vol. 198, pp. 3552.CrossRefGoogle Scholar
Mallah, T., Thiebaut, S., Verdaguer, M., and Veillet, P. (1993). Science 262, 15541557.CrossRefGoogle Scholar
Manriquez, J.M., Yee, G.T., McLean, R.S., Epstein, A.J., and Miller, J.S. (1991). Science 252, 14151417.Google Scholar
Miller, J.S., Epstein, A.J., and Reiff, W.M. (1988). Chem. Rev. 88, 201220 and references therein.Google Scholar
Miller, J.S. (1991). Molecular Magnetic Materials (Kluwer, Dordrecht), NATO ASI Series, Series E, Vol. 198, pp. 151158.Google Scholar
Morgenstern-Badarau, I., Cocco, D., Desideri, A., Rotilio, G., Jordanov, J., and Dupre, N.J. (1986), J. Am. Chem. Soc. 108, 300306.Google Scholar
Rey, P. (1991). Molecular Magnetic Materials (Kluwer, Dordrecht), NATO ASI Series, Series E, Vol. 198, pp. 203214.CrossRefGoogle Scholar
Rietveld, H.M. (1969). J. Appl. Crystallogr. 2, 6571.CrossRefGoogle Scholar
Rigamonti, R. (1937). Gazzetta Chimica Italiana 67, 137145.Google Scholar
Rigamonti, R. (1938). Gazzetta Chimica Italiana 68, 803809.Google Scholar
Rodriguez-Carvajal, J. (1992). Guide of the FullProf program, unpublished.Google Scholar
van Bever, A. K. (1938). Rec. Trav. Chim. Pays. Bas. 57, 12591268.Google Scholar
Willet, R.D., Gatteschi, D., and Kahn, O. (1985). Magneto-structural Correlations in Exchange Coupled Systems (Reidel, Dordrecht), NATO ASI Series, Series C, Vol. 140.Google Scholar
Young, R.A., and Wiles, D.B. (1981). J. Appl. Crystallogr. 14, 149151.Google Scholar
Young, R.A., and Wiles, D.B. (1982). J. Appl. Crystallogr. 15, 430438.Google Scholar
Zilberman, M.V., Kuznecov, V.G., and Volkhin, V.V. (1974). Zh. Neorg. Khim. 19, 18381841.Google Scholar