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Structural characterization of dimercury(1+) pentacyanonitrosylferrate(2), Hg2[Fe(CN)5NO]

Published online by Cambridge University Press:  10 January 2013

V. Venegas
Affiliation:
Escuela Superior de Física y Matemáticas, Departamento de Ciencia de Materiales, Instituto Politécnico Nacional, UP-ALM, Edif. 9. Lindavista 07738, México D.F., México
G. Rueda-Morales
Affiliation:
Escuela Superior de Física y Matemáticas, Departamento de Física, Instituto Politécnico Nacional, UP-ALM, Edif. 9. Lindavista 07738, México D.F., México
E. Reguera
Affiliation:
Escuela Superior de Física y Matemáticas, Departamento de Física, Instituto Politécnico Nacional, UP-ALM, Edif. 9. Lindavista 07738, México D.F., México
F. Caleyo
Affiliation:
Instituto Nacional de Investigaciones Nucleares, G. Ciencia de Materiales, AP 18-1027, Col. Escandón, México 11801, D.F., México

Abstract

The titled compound, Hg2[Fe(CN)5NO], was synthesized and studied by X-ray powder diffraction, infrared spectroscopy, Mössbauer spectroscopy, and atomic force microscopy. The results arising from this study indicate that this compound is anhydrous and crystallizes in the P222 orthorhombic symmetry. The unit cell parameters were quantified as a=16.5905(9) Å, b=12.3145(8) Å, and c=8.7576(5) Å. The measured and calculated density values are Dm=1.149 g/cm3 and Dc=1.145 g/cm3, respectively, with Z=2.

Type
New Diffraction Data
Copyright
Copyright © Cambridge University Press 2000

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