Skip to main content Accessibility help
×
Home

X-Ray Absorption Studies of Ti/Polymer and Cr/Polymer Interfaces

  • R. L. Opila (a1), K. Konstadinidis (a1), A. O. Ibidunni (a2), A. J. Davenport (a2) and H. S. Isaacs (a3)...

Abstract

The interface formed between metals, Ti and Cr, and polymers, epoxy and triazine, have been studied, nondestructively, using x-ray absorption spectroscopy. The metals were sputtered onto the polymer surfaces. Titanium reacts extensively, up to Ti thicknesses of 100 Å while Cr remains primarily metallic. In situ heating at 200°C increases the extent of reaction for both metals. Heating has a greater effect on metal/epoxy interfaces than metal/triazine. Titanium and Cr were ion implanted into the polymer in order to determine the interactions of isolated metal atoms with the polymer. Titanium and Cr appear to form oxides as the final reaction product, and the Ti is tetrahedrally coordinated.

Copyright

References

Hide All
1. Konstadinidis, K., Opila, R. L., Miller, A. C., Taylor, J. A., J. Adhesion, In press.
2. Ho, P. S., Hahn, P. O., Bartha, J. W., Rubloff, G. W., Legoues, F. K., and Silverman, B. D., J. Vac. Sci. Technol. A3, 739 (1985).
3. Haight, R., White, R. C., Silverman, B. D., and Ho, P. S., J. Vac. Sci. Technol. A6, 2188 (1988).
4. Bartha, J. W., Hahn, P. O., Legoues, F., and Ho, P. S., J. Vac. Sci. Technol. A3, 1390 (1985).
5. Hahn, P. O., Rubloff, G. W., and Ho, P. S., J. Vac. Sci. Technol. A2, 756 (1984).
6. Hahn, P. O., Rubloff, G. W., Bartha, J. W., Legoues, F., Tromp, R., Ho, P. S., Mat. Res. Soc. Symp. Proc., 40, Materials Research Society, p. 251 (1985).
7. M.Tromp, R., Legoues, F., and Ho, P. S., J. Vac. Sci. Technol. A3, 782 (1985).
8. Silverman, B. D., Sanda, P. N., and Ho, P. S., J. Polym. Sci., 23, 2857 (1985).
9. Opila, R. L., Masaitis, R. L., Ibidunni, A. O., Davenport, A. J., Isaacs, H. S., and Taylor, J. A., submitted to J. Electrochem. Soc.
10. Bianconi, A., Fritsch, E., Calas, G., and Petiau, J., Phys. Rev. B32, 4292 (1985).
11. Wong, J., Lytle, F. W., Messmer, R. P., and Maylotte, D. H., Phys. Rev., B30, 5596 (1984).
12. Greegor, R. B., Lytle, F. W., Sandstrom, D. R., Wong, J., and Schulz, P., J. Non-Cryst. Solids, 55, 27 (1983).
13. Kutzler, F. W., Natoli, C. R., Misemer, D. K., Doniach, S., and Hodgson, K. O., J. Chem. Phys., 73, 3274 (1980).

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 0 *
Loading metrics...

Abstract views

Total abstract views: 0 *
Loading metrics...

* Views captured on Cambridge Core between <date>. This data will be updated every 24 hours.

Usage data cannot currently be displayed