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Xps Study of Ni-Fe Manganite Thermistor Material

  • D. N. Braski (a1), N. R. Osborne (a2) and J. M. Zurbuchen (a3)


The resistivity of the as-fabricated thermistor material, nickel-iron-manganite, changes during initial aging in the temperature range of 150-300ºC before becoming stable.X-ray photoelectron spectroscopy (XPS) was used to determine if any valency change or chemical shift of the cations or oxygen occurred during aging. The goal of the study was to identify any ionic changes that might affect thermistor stability. The only observed changes in 2p 3/2 peaks due to aging were those related to Ni ions; the same peaks for Mn, Fe, and the 0-Is peak were unchanged. The changes in the Ni 2p 3/2 peak may possibly be related to: (a) the migration of Ni2+ ions from octahedral to tetrahedral sites, (b) subtle changes in the energy states of Ni2+ which promoted a more stable ionic structure, or (c) the presence of Ni3+ ions, some of which revert to Ni2s+.



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1. Kingery, W. D., Introduction to Ceramics. John Wiley & Sons, Inc., N.Y. (1963) p115.
2. Hashemi, T. and Brinkman, A. W., J. Mater. Res. Vol.7, No. 5 1278 (1992).
3. Foord, J. S., Jackman, R. B. and Allen, G. C., Phil Mag. A Vol. 49, No. 5 657 (1984).
4. Brabers, V. A. M., Setten, F. M. van and Knapen, P. S. A., J. of Solid State Chem. 49, 93 (1983).
5. Ng, K. T. and Hercules, D. M., J. of Phys. Chem., Vol. 80, No. 19, 2094 (1976).
6. Baltzer, P. K. ad White, J. G., J. Appl. Phys., Vol.29, No. 3, 445 (1958).
7. Bhandage, G. T. and Keer, H. V., J. Phys. C: Solid State Phys., Vol. 9, 1325 (1976).
8. Macklen, E. D., J. Phys. Chem. Solids, Vol. 47, No. 11, 1073 (1986).
9. Moulder, J. F., Stickle, W. F., Sobol, P. E., and Bomben, K. D., Handbook of X-ray Photoelectron Spectroscopy, Ed. Chastain, J. (Perkin-Elmer, 1992).
10. Mclntyreand, N. S. Cook, M. G., Anal. Chem., Vol. 47, No. 13, 2208 (1975).
11. Evans, W. T. and Schlesinger, M., J. Electrochem. Sot., Vol 141, No. 1, 78 (1994).
12. Briggs, D. and Seah, M. P., Practical Surface Analysis. 2nd Edition. Vol. 1 - Auger and X-ray Photoelectron Spectroscopy, (John Wiley & Sons, N.Y., 1990) p.505.
13. Sinha, A. P. B., Sanjana, N. N. and Biswas, A. B., Acta Cryst. 10, 439 (1957).
14. Blatzer, P. K. and White, J. G., J, appl. Phys. 29, 445 (1958).
15. Larson, E. G., Arnott, R. J., Wickham, D. G., J. Phys. Chem Solids 23, 1771 (1962)
16. Vernon, G. A., Stucky, G. and Carlson, T. A., Inorg. Chem. 15, No. 2, 278 (1976).
17. Beard, B. C., Sandusky, H. W., Glancy, B. C. and Elban, W. L., Surface and Interface Anal. Vol. 20, 140 (1993).
18. More, K. L., Oak Ridge National Laboratory, private communication.
19. Brabers, V. A. M. and Terhell, J. C. J. M., Phys. Stat. Sol. (a) 69, 325 (1962).

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Xps Study of Ni-Fe Manganite Thermistor Material

  • D. N. Braski (a1), N. R. Osborne (a2) and J. M. Zurbuchen (a3)


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