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Wetting Of Ion Containg Polymers: Micelles Versus Molecular Absorption

  • T. A. Hill (a1), X. Jiao (a1), C. W. Martin (a1), D. D. Demarteau (a1) and D. Perahia (a1)...


The wetting behavior of perfluorinated ionomers has been investigated as a function of polymer-surface interaction, the nature of the counter-ion and the structure of the polymer in the solvent from which it has been cast onto the surface. Two different ion-containing polymers, with a per-fluoro-carbon backbone were studied. They differ in the chemical composition and the polarity of their side chains. AFM results together with neutron reflectivity, light scattering and surface tension measurements had shown that the structure of the polymer in the parent solution has a profound effect on the wetting properties as well as the surface structure of the polymers.


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«1» Patel, S.,Tirrell, M., and Hadziioannou, G., Colloid Surf. 31,157,(1988); MRS Bulletin 21, No. 1 (1996); J. Klein, E. Kumacheva, D. Mahalu, D. Perahia, and L. J. Fetters, Nature, 370, 634, (1994); M. Murat, G. S. Grest, K. Kremer, Phys. Lett.. 42, 401 (1998).
«2» Perahia, D.,Weisler, D.,Satija, S. K.,Fetters, L. J.,Sinha, S. K., and Milner, S. T., Phys. Rev. Lett. 72, 100, 1994; Auroy, P.,Auvray, L., and L. L'eger, Macromolecules, 24, 5158, (1991).
«3» Ionomers. Synthesis, Structure, Properties and applications Edit: M. R. Tant, K. A. Mauritz and G. L. Wilkes, lackie Accademic & Professional, (1997).
«4» Reiter, G., PRL, 68,75,1992; Reiter, G.,Auroy, P.,Auvrey, L., Macromolecules, 29, 2150, (1996); Klein et. al. Macromolecules, 31, 422, (1998)
«5» Karim, Feng, A., Weiss, R. A.,Douglas, J. F. and Han, C., PRL, 31, 484, (1998)
«6» Zawdzinski, T. A. Jr, Gottesfeld, S.,Shoichet, S. and MACarthy, T. J., J. Appl. Elecrochem., 23, 86, (1993); C. R. Martin et al., J. Elecrtochem. Soc. 139, 1634, (1992)
«7» Smith, N. S., Martin, Charles W. and Creager, S. E., privet comunication.
«8» Li, J. Y.,Peiffer, D. G. and Chu, B., Marcomolecules, 26, 4006, (1993)
«9» Tsuchida, E., Pure Appl. Chem, A31 1, (1994)
«10» Yu, K. and Eisenberg, A., Macromolecules, 29, 6359, 1996; L. Zhang, and A Eisenberg, Science, 268, 1728, (1995)
«11» Orler, E. B.,Calhun, B. H. and Moore, R. B., Macromolecules, 29, 5965, (1996)
«12» Su, S. and Mauritz, K., Macromolecules, 27, 2079, (1994)
«13» Albert, P.,Dreyfus, B.,Gebel, G.,Nakamura, N.,Pineri, M., and Volino, F., Journal de-Physic-France, 49, 2101, (1988)
«14» Martin, C. W. et. al. in ACS Symp. Ser., edited by Ultracki, L.A. and Weiss, R. A. ( 395, 370,1989)
«15» Demarteau, D. D., J. Fluorine Chem., 72, 203, (1995); E. Tsuchida et. al. Macromolecules, 31, 403, (1998).
«16» Martin, C. W.,Gordon, T. D.,Baker, S. H., and Davila, M., “Forming thin, durable coatings of ion-containing polymers on selected substrates”, US 5,718,947 (1998).
«17» Perahia, D.,Hill, T. A. and Martin, C. W., DOE workshop on Fuel cells, April 1998 Las Vegas; Martin, C. W.,Hill, T. A., and Perahia, D., APS meeting 1998.

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Wetting Of Ion Containg Polymers: Micelles Versus Molecular Absorption

  • T. A. Hill (a1), X. Jiao (a1), C. W. Martin (a1), D. D. Demarteau (a1) and D. Perahia (a1)...


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