Skip to main content Accessibility help
×
Home

Unimolecular Precursors to Binary Metal Sulfides: Mechanistic and Structural Correlations

  • Rodney D. Schluter (a1), Gertrude Kräuter (a1) and William S. Rees (a1)

Abstract

The roles which ligand size and stability play in influencing solid-state thermolyses products and phases are developed for a group of metal thiolate compounds. The exploration includes Pb(SR)2 [R = t-Bu, i-Bu, s-Bu], Cd(SR*)2 [ R* = i-Pr, I-Bu, Bz], ClHgSR** [ R** = i- Pr, neo-Pent, Bz] and In(SR***)3 [R*** = 2,4,6-(i-Pr)3C6H2, 2-CH3O-5-CH3C6H3, o- C6H4CH2N(CH3)2]. In several examples, the precursors have been characterized by single crystal X-ray diffraction. In most cases, solid-state decomposition products have been identified by XRPD, and volatile decomposition products have been identified by GC/MS. All precursors have been studied by TGA.

Copyright

References

Hide All
1. a) Cowley, A. H. and Jones, R. A., Angew. Chem. Int. Ed. Engl. 28, 1208 (1989); b) A. H. Cowley and R. A. Jones, Polyhedron 13, 1149 (1994).
2. a) MacInnes, A. N., Power, M. B. and Barron, A. R., Chem. Mater. 4, 11 (1992); b) W. S. Rees, Jr., D. M. Green, T. J. Anderson, E. Bretschneider, B. Pathangey, C. Park, J. Kim, J. Electron. Mater. 21, 361 (1992); c) G. Kräuter and W. S. Rees, Jr., J. Mater. Chem. 5, 1265 (1995).
3. a) Kräuter, G., Favreau, P. and Rees, W. S. Jr., Chem. Mater. 6, 543 (1994); b) W. S. Rees, Jr. and G. Kräuter, Phosphorus, Sulfur, and Silicon 87, 219 (1994); c) G. Krauter, V. L. Goedken, B. Neumuller and W. S. Rees, Jr., Mat. Res. Soc. Symp. Proc. 327, 35 (1994); d) W. S. Rees, Jr. and G. Krauter, Mat. Res. Soc. Symp. Proc. 327, 3 (1994); e) G. Krauter, B. Neumuiller, V. L. Goedken, and W. S. Rees, Jr., Chem. Mater., in press (1996).
4. Steigerwald, M. L. and Sprinkle, C. R., J. Am. Chem. Soc. 109, 7200 (1987).
5. Kumar, R., Mabrouk, H. E., Tuck, D. G., J. Chem. Soc., Dalton Trans. 1045 (1988).
6. Bradley, D. C. and Marsh, C. H., Chem. Ind., 361 (1967).
7. Krauter, G. and Rees, W. S., Jr., submitted for publication.
8. Morrison, R. T. and Boyd, R. N., Organic Chemistry, 2nd ed., Allyn and Bacon, Boston, 1966.
9. Schluter, R. D., Luten, H. A. and Rees, W. S., Jr., Mat. Res. Soc. Symp. Proc. in press (1996).

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 0 *
Loading metrics...

Abstract views

Total abstract views: 0 *
Loading metrics...

* Views captured on Cambridge Core between <date>. This data will be updated every 24 hours.

Usage data cannot currently be displayed