Hostname: page-component-cd9895bd7-p9bg8 Total loading time: 0 Render date: 2024-12-21T14:54:15.553Z Has data issue: false hasContentIssue false
  • English
  • Français

Two Pillared Three-Dimensional Inorganic/Organic Hybrid Structures Composed of Bimetallic Layers Bridged by Exo-bidentate Ligands

Published online by Cambridge University Press:  18 March 2011

Long Pan ,
Xiaoying Huang  and
Jing Li
Long Pan
Affiliation:
Department of Chemistry, Rutgers University, Camden, NJ 08102, USA
Xiaoying Huang
Affiliation:
Department of Chemistry, Rutgers University, Camden, NJ 08102, USA
Jing Li
Affiliation:
Department of Chemistry, Rutgers University, Camden, NJ 08102, USA
Get access

Abstract

The hydrothermal reactions of Cu(NO3)2.3H2O, K2CrO4 and exo-bidentate ligand bpy/bpe, (bpy = 4,4'-bipyridine, bpe = trans-1,2-bis(4-pyridyl)ethylene) result in two pillared 3D organic-inorganic hybrid compounds. Both contain bimetallic layers of copper(II) cations and chromate anions, which are directly connected by different organic ligands, leading to pillared structures with varying pillar length and thickness of layers. Crystal data for [Cu3(CrO4)2(OH)2(bpy)2] (1): triclinic, P1, a = 5.358(1), b = 5.603(1), c = 13.515(3) Å, α = 81.78(3), γ = 86.56(3), Å3 = 79.75(3)°, V = 394.91(13) Å3, Z = 1; [CuCrO4(bpe)] (2): monoclinic, C2/c, a = 23.282(5), b = 11.917(2), c = 9.726(2) Å, β = 112.99(3)°, V = 2484.2(8) Å3, Z = 8.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 658: Symposium GG – Solid-State Chemistry of Inorganic Materials III , 2000 , GG67.1
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Yaghi, O. M., Li, H., Davis, C., Richardson, D., and Groy, T. L., Acct. Chem. Res., 31, 474 (1998).Google Scholar
2. Batten, S. R., and Robson, R., Angew. Chem., 37, 1461 (1998).Google Scholar
3. Clearfield, A., Chem. Mater. 10, 2801 (1998).Google Scholar
4. Li, D., and Kaneko, K., J. Phys. Chem. B., 104, 8940 (2000).Google Scholar
5. Hagrman, P. J., Hagrman, D., and Zubieta, J., Angew. Chem., 38, 2639 (1999).Google Scholar
6. Bensch, W., Seferiadis, N., and Oswald, H. R., Inorg. Chim. Acta., 126, 113 (1987).Google Scholar
7. Kopfmann, G, and Hubber, R., Acta Crystallogr, A24, 348 (1968).Google Scholar
8. Sheldrick, G. M., SHELX-97: program for structure refinement; University of Goettingen: Germany, 1997.Google Scholar
9. Smith, G., O'Relly, E. J., Kennard, C. H. L., and Mak, T. C. W., Inorg. Chim. Acta, 65, L219 (1982)Google Scholar
10. Hagrman, D., Haushalter, R. C., and Zubieta, J., Chem. Mater., 10, 361 (1998).Google Scholar