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Thermodynamical Estimations on the Amount of Liquid Phase During Reaction Synthesis of Nickel-Aluminides

Published online by Cambridge University Press:  22 February 2011

Seiji Miura
Affiliation:
Precision and Intelligence Laboratory, Tokyo Institute of Technology, Yokohama 226, Japan.
Yoshinao Mishima
Affiliation:
Precision and Intelligence Laboratory, Tokyo Institute of Technology, Yokohama 226, Japan.
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Abstract

The amounts of intermetallic compounds and liquid phase are estimated as a function of temperature during reaction syntheses for Ni–Al binary alloys having arbitrary compositions under adiabatic conditions. It is assumed that the phases that would present during the process are only those appearing in the equilibrium binary phase diagram. Calculations are done by using available data on heat of formation of intermetallic compounds and those on enthalpy of liquid phase. The results obtained arc discussed in view of the estimation and control of the amount of liquid phase, which is significant for the densification and shape change of materials.

Type
Research Article
Copyright
Copyright © Materials Research Society 1995

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