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Theory of Spinodal Decomposition in Very Viscous Binary Liquid Mixtures

Published online by Cambridge University Press:  16 February 2011

Josef Jäckle
Affiliation:
University of Konstanz, Fakultät für Physik, D-7750 Konstanz, Germany
M. Pieroth
Affiliation:
University of Konstanz, Fakultät für Physik, D-7750 Konstanz, Germany
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Abstract

We have developed a theory for the evolution of concentration fluctuations after a temperature quench which takes the effect of slow structural relaxation into account. In its linear and non-linear forms, it generalizes the theories of Cahn, Hilliard and Cook, and of Langer, Bar-on and Miller.

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

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References

[1] Pieroth, M., doctoral diss., University of Konstanz, 1990.Google Scholar
[2] Gunton, J.D., San Miguel, M., and Sahni, P., in Phase Transitions and Critical Phenomena Vol.8, edited by C., Domb and J.L., Lebowitz (Academic, New York, 1983), p. 267.Google Scholar
[3] Binder, K., in Materials Science and Technology Vol.5, edited by P., Haasen (VCH-Verlagsges., Weinheim, 1990).Google Scholar
[4] Komura, S, Phase Transitions 12, 3 (1988).CrossRefGoogle Scholar
[5] Jäckle, J. and Frisch, H.L., J. Polym. Sci., Polym. Phys. Edn. 23, 675 (1985); J. Chem. Phys. 85, 1621 (1986).CrossRefGoogle Scholar
[6] Durning, C.J., J. Polym. Sci., Polym. Phys. Edn. 23, 1831 (1985).CrossRefGoogle Scholar
[7] Binder, K., Frisch, H.L., and Jäckle, J., J. Chem. Phys. 85, 1505 (1986).CrossRefGoogle Scholar
[8] Kishimoto, A., Fujita, H., Odani, H., Kurata, M., and Tamura, M., J. Phys. Chem. 64, 594 (1960).CrossRefGoogle Scholar
[9] Crank, J., The Mathematics of Diffusion 2nd edn. (Clarendon, Oxford, 1975).Google Scholar
[10] Cook, H.E., Acta Metall. 18, 297 (1970).CrossRefGoogle Scholar
[11] Langer, J. S., Bar-on, M., and Miller, H.D., Phys. Rev. A 11, 1417 (1975).CrossRefGoogle Scholar
[12] Jäckle, J. and Pieroth, M., J. Phys.: Condens. Matter 2, 4963 (1990).Google Scholar
[13] Jäckle, J. and Pieroth, M., Z. Phys. 72, 25 (1988).CrossRefGoogle Scholar
[14] Strobl, G.R., Macromolecules 18, 558 (1985).CrossRefGoogle Scholar
[15] Schwahn, D., Hahn, K., Streib, J., and Springer, T. Google Scholar
[16] Pieroth, M. and Jäckle, J., to be publ.Google Scholar