Hostname: page-component-8448b6f56d-jr42d Total loading time: 0 Render date: 2024-04-24T11:58:15.741Z Has data issue: false hasContentIssue false

Tailor-Made Nanostructured Ion Selective MCM-48 Membranes

Published online by Cambridge University Press:  10 February 2011

Sankhanilay Roy Chowdhury
Affiliation:
MESA Research Institute, University of Twente P.O. Box 217, 7500AE, Enschede, The Netherlands
Riaan Schmuhl
Affiliation:
MESA Research Institute, University of Twente P.O. Box 217, 7500AE, Enschede, The Netherlands
Klaas Keizer
Affiliation:
MESA Research Institute, University of Twente P.O. Box 217, 7500AE, Enschede, The Netherlands
Albert van den Berg
Affiliation:
MESA Research Institute, University of Twente P.O. Box 217, 7500AE, Enschede, The Netherlands
Johan E. ten Elshof
Affiliation:
MESA Research Institute, University of Twente P.O. Box 217, 7500AE, Enschede, The Netherlands
Dave H.A. Blank
Affiliation:
MESA Research Institute, University of Twente P.O. Box 217, 7500AE, Enschede, The Netherlands
Get access

Abstract

Mesoporous templated MCM-48 silica was prepared using a C16 surfactant as template. The MCM-48 powders and thin films were characterized by different techniques. Two types of porous supports were used, namely macroporous á-alumina and silicon microsieves. The supported MCM-48 layers were applied as liquid permeable membranes in pressure-driven nanofiltration and electric field-mediated ion transport experiments.

Type
Research Article
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Beck, J.S., Vartuli, J.C., Roth, W.J., Leonowicz, M.E., Kresge, C.T., Schmitt, K.D., Chu, C.T.W., Olson, D.H., Sheppard, E.W., McCullen, S.B., Higgins, J.B. and Schlenkert, J.L., J. Am. Chem. Soc. 114, 10834 (1992)Google Scholar
2. Zhao, D., Yang, P., Margolese, D.I., Chmelka, B.F. and Stucky, G.D., Chem. Commun. 2499 (1998).Google Scholar
3. Zhao, D., Yang, P., Melosh, N., Feng, J., Chmelka, B.F. and Stucky, G.D., Adv. Mater. 10, 1380 (1998)Google Scholar
4. Yang, H., Coombs, N., Sokolov, I. and Ozin, G.A., J. Mater. Chem. 7, 1285 (1997)Google Scholar
5. Klotz, M., Ayral, A., Guizard, C. and Cot, L., Sep. Purif. Tech. 25, 71 (2001)Google Scholar
6. Anderson, M.W., Simplified description of MCM-48, Zeolites 19, 220 (1997)Google Scholar
7. Biesheuvel, P.M. and Lint, W.B.S. de, J. Colloid Interf. Sci. 241, 422 (2001)Google Scholar
8. Micro Total Analysis Systems 2000, ed. Berg, A. van den, Olthuis, W. and Bergveld, P., (Kluwer, 2000).Google Scholar
9. Kemery, P.J., Steehler, J.K. and Bohn, P.W., Langmuir 14, 2884 (1998)Google Scholar
10. Kuo, T.C., Sloan, L.A., Sweedler, J.V. and Bohn, P.W., Langmuir 17, 6298 (2001)Google Scholar
11. Nishizawa, M., Menon, V.P. and Martin, C.R., Science 268, 700 (1995)Google Scholar
12. Benes, N., Nijmeijer, A. and Verweij, H., “Mesoporous silica membranes”, in: Kanellopoulos, N.K. (Ed.), Recent advances in gas separation by microporous ceramic membranes, (Elsevier Amsterdam, 2000.) pp.335372.Google Scholar
13. Zhou, Honma H.S., Kundu, D. and Endo, A., Adv. Mater. 12, 1529 (2000)Google Scholar
14. Chowdhury, S. Roy, Elshof, J.E. ten, Benes, N.E. and Keizer, K., Desalination 144, 41 (2002)Google Scholar