Hostname: page-component-8448b6f56d-wq2xx Total loading time: 0 Render date: 2024-04-20T04:21:21.869Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis of Low Density Microcellular Activated Carbon Supported Nanophase Pt and Pd Particles and Study of Its Catalytic Properties

Published online by Cambridge University Press:  15 February 2011

Hong-Ming Lin ,
Ching-Shung Huang  and
Chi-Ming Hsu
Hong-Ming Lin
Affiliation:
Department of Materials Engineering, Tatung Institute of Technology, Taipei, Taiwan, R.O.C
Ching-Shung Huang
Affiliation:
Department of Materials Engineering, Tatung Institute of Technology, Taipei, Taiwan, R.O.C
Chi-Ming Hsu
Affiliation:
Department of Materials Engineering, Tatung Institute of Technology, Taipei, Taiwan, R.O.C
Get access

Abstract

The use of activated low density microcellular carbon (LDMC) as a catalysis supporter for nanophase Pt or Pd particles has been successfully developed in this study. The good dispersion and interfacial properties of nanophase Pt or Pd particles on activated LDMC are formed by using an impregnation and sintering process. The interfacial structures are examined by TEM, HRTEM and an image analyst system. No preferred orientation of interfacial bonding has been found between nanophase Pt and activated LDMC. The activated LDMC supported Pt or Pd catalysts have the high reactivity which can complete hydrogenation and oxidation of CO gas at low temperatures (<453 K). The catalytic activity of CO hydrogenation is increased as the size of the nanophase Pt and Pd particles decreases.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 351: Symposium V – Molecularly Designed Ultrafine/Nanostructured Materials , 1994 , 281
Copyright
Copyright © Materials Research Society 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Somorjai, G. A., Catal. Rev., 7 (1972) 87.Google Scholar
2. Takasu, Y., Unwin, R., Tesche, B., Bradshaw, A. M. and Grunze, M., Surf. Soc., 77(1978)219.Google Scholar
3. Lemay, J. D., Hopper, R. W., Hrubesh, L. W., and Pekala, R. W., MRS Bulletin/December, (1990) 19–41.Google Scholar
4. Jung, H-J, Walker, P. L. Jr. and Vanice, M. A., J. Catal., 75 (1982) 416.Google Scholar
5. Rodriguez-Reinoso, F., Rodriguez-Ramos, I., Guerrero-Ruiz, A., and Lopez-Gonalez, J. D., Appl. Catal., 21 (1986) 251.Google Scholar
6. Jung, H-J, Vannice, M. A., Mulay, L. N., Stanfield, R. M., and Delgass, W. N., J. Catal., 76 (1982) 208.Google Scholar
7. Venter, J. J., Kaminsky, M., Geofroy, G. L., and Vannice, M. A., J. Catal., 103 (1887) 450.Google Scholar
8. Todo, N., Nishijima, N., Ueno, A., Kurita, M., Hagiwara, H., Sato, T. and Kiyozumi, Y., Chem. Lett., (1976) 897.Google Scholar
9. Kasaoka, S., Sasaoka, E. and Iwasaki, H., Bull. Chem. Soc. Jpn., 62 (1989) 1226.Google Scholar
10. Chen, A. A., Vannice, M. A, and Phillips, J., J. Phys. Chem., 91 (1987) 6257.Google Scholar
11. Lin, Hong-Ming, Hsieh, Shu-Huei, Lee, Pee-Yew, Lai, Ming-Shung and Wu, Jie-Shing, Materials Chemistry and Physics, 34 (1993) 205–213.Google Scholar