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Synthesis of CuInS2-ZnS Alloyed Nanorods and Hybrid Nanostructures

Published online by Cambridge University Press:  28 August 2015

Jie Li ,
Jürgen Parisi  and
Joanna Kolny-Olesiak
Jie Li
Affiliation:
Energy and Semiconductor Research Laboratory, Department of Physics, Carl von Ossietzky University of Oldenburg, 26129 Oldenburg, Germany
Jürgen Parisi
Affiliation:
Energy and Semiconductor Research Laboratory, Department of Physics, Carl von Ossietzky University of Oldenburg, 26129 Oldenburg, Germany
Joanna Kolny-Olesiak
Affiliation:
Energy and Semiconductor Research Laboratory, Department of Physics, Carl von Ossietzky University of Oldenburg, 26129 Oldenburg, Germany
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Abstract

Alloyed nanorods and hybrid nanostructures composed of CuInS2 and ZnS were synthesized by heating-up and hot-injection procedures. The synthesis starts with the formation of copper sulfide seeds, which are subsequently converted to copper sulfide – copper indium zinc sulfide hybrid nanostructures, by incorporation of indium and zinc ions. The fraction of ZnS within the alloyed material could be controlled by the amount of the Zn precursor in the reaction solution. In reactions with higher zinc precursor concentrations, at longer reaction times L-shaped hybrid nanostructures are formed of CuInS2-ZnS alloy and ZnS. An additional injection of the Zn-precursor into the reaction solution results in the formation of U-shaped hybrid nanostructures.

Keywords

nanoscalenanostructuremorphology
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1780: Symposium N – From Molecules to Colloidal Compound Semiconductor Nanocrystals―Advances in Mechanism-Enabled Design and Syntheses , 2015 , mrss15-2136281
Copyright
Copyright © Materials Research Society 2015 

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