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Synthesis and Incorporation of Thienylene Vinylene Oligomers in Main-Chain Copolymers

Published online by Cambridge University Press:  10 February 2011

L. G. Madrigal ,
E. H. Elandaloussi  and
C. W. Spangler
L. G. Madrigal
Affiliation:
Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, uchcs@ earth.oscs.montana.edu
E. H. Elandaloussi
Affiliation:
Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, uchcs@ earth.oscs.montana.edu
C. W. Spangler
Affiliation:
Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, uchcs@ earth.oscs.montana.edu
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Abstract

Poly [2,5-thienylene vinylene] (PTV) has been studied extensively over the past decade for both its metallic conductivity behavior upon chemical doping, as well as its interesting third order nonlinear optical properties. PTV oligomers have been synthesized by our group 1, as well as others 2, and the formation of polaron-like radical-cations or bipolaron-like dications by oxidative doping has been demonstrated. In this paper we describe a general synthetic approach to PTV oligomers functionalized for copolymer formation by step-growth reaction.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 488: Symposium J – Electrical, Optical & Magnetic Properties of Organic IV , 1997 , 647
Copyright
Copyright © Materials Research Society 1998

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References

1. Spangler, C. W. and Liu, P.-K., Synth. Metals 44, 259 (1991).Google Scholar
2. Elandaloussi, E. H., Frère, P. and Roncali, J., J. Chem. Soc. Chem. Commun. 1997, 301.Google Scholar
3. Spangler, C. W. and He, M. in Handbook of Organic Conductive Molecules and Polymers: Vol.2, edited by Nalwa, H. S. (John Wiley & Sons Ltd., Chichester, 1997) pp. 389–414.Google Scholar
4. Spangler, C. W. and He, M. in Electrical, Optical and Magnetic Properties of Organic Solid State Materials III, edited by Jen, A. K.-Y., Lee, C. Y.-C., Dalton, L. R., Rubner, M. F., Wnek, G. E. and Chiang, L. Y. (Mater. Res. Soc. Proc. 413,. Pittsburgh, PA, 1996) pp. 221–229.Google Scholar
5. Elandaloussi, E. H., Frère, P., Richomme, P., Orduna, J., Garin, J. and Roncali, J., J. Amer. Chem. Soc. 119, 10774 (1997).Google Scholar
6. Kaino, T., Kubodera, K., Kobayashi, H., Kurihara, T., Saito, S., Tsutsuni, T., Tokito, S. and Murata, H., Appl. Phys. Lett. 53(21), 2002 (1988).Google Scholar
7. Luzzati, S., Botta, C., Romanoni, M., Comeretto, D., Tubino, R., Nisoli, M., Cybo-Ottone, A. and De Silvestri, S. in Nonlinear Properties of Organic Materials VI, edited by Möhlmann, G. (Proc. SPIE, 2025, Bellingham, WA, 1993) pp. 450–458.Google Scholar
8. Casstevens, M. K., Burzynski, R., Weibel, J. F., Spangler, C., He, G. and Prasad, P. N. in Nonlinear Optical Liquids and Power Limiters (Proc. SPIE, Bellingham, WA, 1997) pp. 152–159.Google Scholar