Hostname: page-component-78c5997874-xbtfd Total loading time: 0 Render date: 2024-11-19T11:45:32.720Z Has data issue: false hasContentIssue false
  • English
  • Français

Surface and Interfacial Properties in Thin Poly(p-Phenylene vinylene) Multilayers Prepared by Self-Assembly Method

Published online by Cambridge University Press:  21 March 2011

Célio A. M. Borges ,
Alexandre Marletta ,
Roberto M. Faria  and
Francisco E. G. Guimarãaes
Célio A. M. Borges
Affiliation:
Instituto de Física de São Carlos, Universidade de São Paulo, CP 369, 13560-970, São Carlos-SP, Brazil.
Alexandre Marletta
Affiliation:
Instituto de Física de São Carlos, Universidade de São Paulo, CP 369, 13560-970, São Carlos-SP, Brazil.
Roberto M. Faria
Affiliation:
Instituto de Física de São Carlos, Universidade de São Paulo, CP 369, 13560-970, São Carlos-SP, Brazil.
Francisco E. G. Guimarãaes
Affiliation:
Instituto de Física de São Carlos, Universidade de São Paulo, CP 369, 13560-970, São Carlos-SP, Brazil.
Get access

Abstract

In this work we report on the influence of interfaces (metal/film, ITO/film) on the optical properties of ultrathin layers of poly(-phenylene vinylene), PPV, adsorbed by self-assembly. PPV films were prepared exploiting the self-assembly method (SA) in addition to a low temperature conversion process for PPV. Using atomic force microscopy we show that 0.5 nm thick PPV layers can be homogeneously deposited on different metals (50% transmission Au, Cu, Pt, Ag, Cr films), glass and ITO surfaces. Absorption measurements reveal that the transitions involving φ-φ conjugated states are blue shifted to different extents depending on the interface and on the film thickness. This indicates different extensions of interfacial disorder in the PPV layers. The ITO/PPV interface has the highest extension for disorder (∼16 nm) and highest surface roughness (RMS∼2.5 nm) while the lowest values (∼5 nm and 0.6 nm, respectively) were found for the quartz/PPV interface. The metal interface induces significant luminescence quenching and spectral shifts, which depend on the type of metal used. The effect from incorporation of carbonyl and from chemical modifications of the ITO/organic interface during PPV thermal conversion is discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 707: Symposium AA – Self-Assemble Processes in Materials , 2001 , AA10.5.1/DD11.5.1
Copyright
Copyright © Materials Research Society 2002

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Parker, I. D., J. Appl. Phys. 75, 1656, (1994).Google Scholar
2. Mason, M.G., Tang, C.W., Hung, L.-S., Raychaudhuri, P., Madathil, J., Yan, L., Le, Q. T., Gao, Y., Salaneck, W.R., dos, D.A. Santos, Bredas, J.L., J. Appl. Phys. 89, 2756, (2001).Google Scholar
3. Salaneck, W.R., Kugler, Th., Andersson, A., Bröms, P., Birgerson, J., Lögdlund, M., “Conjugated Oligomers, Polymers, and Dendrimers: from Polyacetylene to DNA”, Proceedings of the Fourth Francqui Colloquium, ed. Brédas, J.L. (De Boeck Université, 1998) pp. 41–59.Google Scholar
4. Seki, K., Ito, E., Oji, H., Yoshimura, D., Hayashi, N., Sakurai, Y., Hosoi, Y., Yokoyama, T., Imai, T., Ouchi, Y., Synth. Met. 119, 19, (2001).Google Scholar
5. Scott, J. C., Malliaras, G. G., Chem. Phys. Lett. 229, 115, (1999).Google Scholar
6. Schlaf, R., Merritt, C.D., Crisafulli, L.A., Kafafi, Z.H., J. Appl. Phys. 86, 5678, (1999).Google Scholar
7. Marletta, A., Castro, F.A., Gonçalves, D., Oliveira, O.N. Jr, Faria, R.M., Guimarães, F.E.G., Synth. Met. 121, 1447, (2001).Google Scholar
8. Marletta, A., Gonçalves, D., Oliveira, O. N. Jr, Faria, R. M., Guimarães, F. E. G., Adv. Mater. 12, 69, (2000).Google Scholar
9. Bradley, D. D. C., J.Phys. D: Appl. Phys. 20, 1389, (1987).Google Scholar
10. Lobo, R.F.M., Pereira-da-Silva, M. A., Raposo, M., Faria, R. M. and Oliveira, O. N. Jr, Nanotechnology 10, 389, (1999).Google Scholar
11. Fou, A.C., Onitsuka, O., Rubner, M.F., J. Apll. Phys. 79, 7501, (1996).Google Scholar
12. Hong, H., Davidov, D., Chayet, H., Faraggi, E.Z., Tarabia, M., Avny, Y., Neumann, R., Kirstein, S., Supramol. Sci. 4, 67, (1997).Google Scholar