Hostname: page-component-cd9895bd7-gxg78 Total loading time: 0 Render date: 2024-12-22T06:32:56.313Z Has data issue: false hasContentIssue false
  • English
  • Français

A Study of the Oxygen Transport Kinetics in SrFeO3-x

Published online by Cambridge University Press:  11 February 2011

Jiho Yoo  and
Allan J. Jacobson
Jiho Yoo
Affiliation:
Center for Materials Chemistry, University of Houston, 4800 Calhoun Rd., Houston, TX, USA, 77204–5002
Allan J. Jacobson
Affiliation:
Center for Materials Chemistry, University of Houston, 4800 Calhoun Rd., Houston, TX, USA, 77204–5002
Get access

Abstract

Experimental results from electrical conductivity relaxation (ECR) measurements on SrFeO3-x are described. Values of Dchem and kchem were obtained by monitoring the variation of the time dependence of the electrical conductivity after an abrupt change in the oxygen partial pressure. Values for the oxygen ion and vacancy diffusion coefficients were calculated from the measured thermodynamic factors and compared with those of other compositions in the series La1-xSrxFeO3-x. The surface exchange coefficients, kchem and kex were also determined.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 756: Symposia EE/FF – Solid-State Ionics – Materials for Fuel Cells and Fuel Processors , 2002 , EE3.10
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Ohno, Y., Nagata, S., and Sato, S., Solid State Ionics, 3/4, 439 (1981)Google Scholar
2. Alcock, C. B., Doshi, R. C., and Shen, Y., Solid State Ionics, 51, 281 (1992)Google Scholar
3. Tunney, J. J. and Post, M. L., Journal of Electroceramics, 5, 63 (2000)Google Scholar
4. Battle, P. D., Gibb, T. C., and Nixon, S., J. Solid State Chem., 79, 75 (1989)Google Scholar
5. van Roosmalen, J. A. M. and Cordfunke, E. H. P., J. Solid State Chem., 93, 212 (1991)Google Scholar
6. Mizusaki, J., Yoshihiro, M., Yamauchi, S. and Fueki, K., J. Solid State Chem., 67, 1 (1987).Google Scholar
7. Takeda, Y., Kanno, K., Takada, T., Yamamoto, O., Takano, M., Nakayama, N., and Bando, Y., J. Solid State Chem., 63, 237 (1986)Google Scholar
8. Kozhevnikov, V. L., Leonidov, I. A., Patrakeev, M. V., Mitberg, E. B., and Poeppelmeier, K. R., J. Solid State Chem., 158, 320 (2000)Google Scholar
9. Nisancioglu, K., and Gür, T. M., Solid State Ionics, 72, 199 (1994)Google Scholar
10. Ishigaki, T., Yamauchi, S., Kishino, K., Mizusaki, J. and Fueki, K., J. Solid State Chem., 73, 179 (1988).Google Scholar
11. Ishigaki, T., Yamauchi, S., Mizusaki, J., and Fueki, K., J. Solid State Chem., 55, 50 (1984)Google Scholar
12. ten Elshof, J. E., Lankhorst, M. H. R. and Bouwmeester, H. J. M., J. Electrochem. Soc., 144(3), 1060 (1997)Google Scholar
13. Bouwmeester, H. J. M., Kruidhof, H. and Burggraaf, A. J., Solid State Ionics, 72, 185 (1994).Google Scholar
14. Ming, Q., Hung, J., Yang, Y. L., Nersesyan, M., Jacobson, A. J., Richardson, J. T., and Luss, D., Combust. Sci. and Tech., 138, 279 (1998)Google Scholar
15. Wang, S., Oxygen transport in mixed conducting perovskite oxides, PhD. Thesis, University of Houston, 2000.Google Scholar
16. Wang, S., Verma, A., Yang, Y. L., Jacobson, A. J., and Abeles, B., Solid State Ionics, 140, 125 (2001)Google Scholar
17. Yoo, J. and Jacobson, A. J., in preparation.Google Scholar
18. Kim, S., Wang, S., Chen, X., Yang, Y. L., Wu, N., Ignatiev, A., Jacobson, A. J., and Abeles, B., J. Electrochem. Soc., 147(6), 2398 (2000).Google Scholar
19. ten Elshof, J. E., Lankhorst, M. H. R., and Bouwmeester, H. J. M., Solid State Ionics, 99, 15 (1997)Google Scholar
20. Kofstad, P., Nonstoichiometry, Diffusion, and Electrical Conductivity in Binary Metal Oxides, (Wiley, New York, 1972)Google Scholar