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Study of Srl−xErxF2+x Luminescent Thin Films Epitaxially Grown on InP (100).

Published online by Cambridge University Press:  21 February 2011

A.S. Barriere
Affiliation:
LEMME, 351 Crs de la Liberation 33405 Talence, France
B. Mombelli
Affiliation:
LEMME, 351 Crs de la Liberation 33405 Talence, France
B.Y. Kim
Affiliation:
LEMME, 351 Crs de la Liberation 33405 Talence, France
S. Raoux
Affiliation:
LEMME, 351 Crs de la Liberation 33405 Talence, France
A. Garcia
Affiliation:
LCS, Univ. Bordeaux I, 351 Crs de la Liberation 33405 Talence, France
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Abstract

Erbium-substituted Srl-xErxF2+x strontium fluoride layers were grown on InP(100) substrates by sublimation under ultra-high vacuum of high purity solid solution powders.

Their composition and the spatial distribution of the basic components were deduced from Rutherford backscattering (RBS), using a nuclear microprobe, and secondary ion mass spectrometry (SIMS). For x lower than 20% it is shown that the film composition is analogous with the initial sintered material and quite homogeneous. The ageing in air of the films was followed by infrared absorption studies. No significant water adsorption was revealed.

The texture of the layers was studied by RBS in channelling condition. For x as high as 15% it is shown that the films are well crystallized and well epitaxially grown on InP (100) substrates.

Infrared emission due to the 4I13/2-4I15/2 electronic transition on the 4f11 inner shells of Er3+ ions (1.53μm), which presents potential applications for optical communications, was studied at room temperature as a function of x. It is demonstrated that the highest luminescence efficiency of these layers corresponds to x upper than 20%.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

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References

REFERENCES

[1] Asano, T., Ishiwara, H., Lee, H.C., Tsutsui, K. and Furukawa, S., Jpn. J. Appl. Phys. 25 (1986) L139.Google Scholar
[2] Kaminskii, A.A., Laser crystals (Springer, New York, 1981).Google Scholar
[3] Gevers, G., Barriere, A.S., Grannec, J., Lozano, L., Blanchard, B.. Phys. Stat. solidi A81 (1984) 105.Google Scholar
[4] Guégan, H.. Ph. D. Thesis, University of Bordeaux I - 1990.Google Scholar
[5] Barrière, A.S., Desbat, B., Fajri, A. EL, Guégan, H. and Tournay, V. Appl. Surf. Sc., 64 (1993) 225.Google Scholar
[6] Llabador, Y., Berthault, D., Gouillaud, J.C., Moretto, P. Nuclear. Inst. and Meth. B49 (1990) 435440.Google Scholar
[7] Barrière, A.S., Fajri, A. EL, Guegan, H., Mombelli, B., Raoux, S. J. Appl. Phys. 71, 2 (1992) 709.Google Scholar
[8] Blasse, G., Bril, A. Philips Tech. Rev. 31, 10 (1970) 304.Google Scholar
[9] Brown, M.R., Thomas, H., Whiting, J.S.S., Shang, W.A. J. Chem. Phys. 50, 2 (1969), 881 Google Scholar
[10] Inta-4f-shell transitions of ER3+ ions in Cal−xErxF2+x thin films grown on Si(100). Barrière, A.S., Raoux, S., Garcia, A., L'Haridon, H., Lambert, B. and Motonnet, D. Proposed for publication, J. Appl. Phys (01/02/93)Google Scholar
[11] Miller, M.P., Wright, J.C. J. Chem. Phys. 71 (1) (1979) 324.Google Scholar
[12] Brown, M.R., Thomas, H., Williams, J.M., Woodward, R.J., Shand, W.A. J. Chem. Phys. 31 (8) (1969) 3321.Google Scholar
[13] Auzel, F. J. of Lumin. 31–32 (1984) 759761.Google Scholar
[14] Favennec, P.N., L'Haridon, H., Moutonnet, D., Salvi, A., Gauneau, M. Jap. J. of Appl. Phys 29–4 (1990) L524.Google Scholar
[15] Galtier, P., Pocholle, J.P., Charasse, M.N., Cremoux, R. de, Hirtz, J.P., Groussin, B., Benyattou, T., Guillot, G. Appl. Phys. Lett. 55–20 (1989) 2105.Google Scholar
[16] Rochaix, C., Rolland, A., Favennec, P.N., Lambert, B., Corre, A. Le, L'Haridon, H., Salvi, M. J. Elect. Mat. 17–5 (1988) 351.Google Scholar
[17] Kurz, M.D., Wright, J.C. J. of Lumin. 15 (1977) 169186.Google Scholar
[18] Amaral, N.C., Maffeo, B., Guenzburger, D. Phys. Stat. Sol. B 117, 141 (1983).Google Scholar
[19] Reau, J.M., Wahbi, M., Sénégas, J. and Hagenmtiller, P. Phys. Stat. Sol. (b) 169, 331 (1992).Google Scholar
[20] Bausa, L.E., Legros, R., Munoz-Yague, A. J. Appl. Phys. 70 (8)- 1991, 4485.Google Scholar