Skip to main content Accessibility help
×
Home

Study of Oxetane Toughened Cationic UV Curable Marine Fouling Release Coating

  • Zhigang Chen (a1), Rachel Wagner (a1), Sandeep Patel (a1), Jongsoo Kim (a1), Shane Stafslien (a1), Justin Daniels (a1), Lyndsi Vander Wal (a1), Chavanin Siripirom (a2) and Bret Chisholm (a1)...

Abstract

To develop a cationic UV curable, tough fouling-release coating for marine vessels, a difunctional oxetane monomer was used to copolymerize with the epoxy-siloxane oligomer at loading levels from 10% to 40% wt.. The resulting coatings showed enhanced solvent resistance, impact resistance and modulus, while remained hydrophobic before and after immersion in artificial sea water. In marine microorganism bioassay, these oxetane toughened coatings showed no leachate toxicity and the coating surfaces were non-toxic to biofilm growth. The fouling removal performance for these coatings was found to be microorganism dependent. Live barnacle reattachment assay showed that the toughened coatings had a removal force comparable to the reference silicone coatings Dow Corning T2 and 3140.

Copyright

References

Hide All
1. Diego, M. Y., Kiil, S., Kim, D. J., Progress in Organic Coatings, 50, 75104 (2004).
2. Iwao, O., Chem.Rev., 103, 34313448 (2003).
3. Anderson, C., Atlar, M., Callow, M., Candries, M., Milne, A., Townsin, R.L., Proceeding of the Institute of Marine Engineering, Science and Technology (IMarEST) Part B: Journal of Marine Design and Operations, 4, 1123 (2003).
4. Chen, Z., Webster, D. C., Polymer, 47, 37153726 (2006).
5. Chen, Z., Webster, D. C., Journal of Polymer Science, Part A: Polymer Chemistry, 44, 44354449 (2006).
6. Stafslien, S., Bahr, J., Daniels, J. A., Wal, J. W. Vander, Nevins, L., Smith, J., Schiele, K., Chisholm, B., Rev. Sci. Instr. (2006), In press.
7. Stafslien, S., Daniels, J. A., Chisholm, B., Christianson, D., Biofouling 23(2007).
8. Ekin, A., Webster, D. C., Daniels, J. W., Stafslien, S. J., Casse, F., Callow, J. A., Callow, M. E., J. Coatings Technol (2007), In press.
9. Stafslien, S., Bahr, J., Feser, J. M., Weisz, J. C., Chisholm, B., Ready, T. E., Boudjouk, P., J. Comb. Chem., 8, 156162 (2006).
10. Casse, F., Stafslien, S., Bahr, J., Daniels, J., Finlay, J., Callow, J., Callow, M., Biofouling, 23, (2007).
11. Sasaki, H., Technical Conference Porceedings - RadTech 2002: The Premier UV/EB Conference & Exhibition, 6478 (2002).
12. Krishnan, S., Christopher, N. W., Ober, K., Finlay, J. A., Callow, M. E., Callow, J. A., Hexemer, A., Sohn, K. E., Kramer, E. J., Fischer, D. A., Biomacromolecules, 7, 14491462 (2006).
13. Mirabedini, S. M., Pazoki, S., Esfandeh, M., Mohseni, M., Akbari, Z., Progress in Organic Coatings, 57, 421429 (2006).
14. Stein, J., Christina, K. T., Wood, Darkangelo., Takemori, Michael., Vallance, Machael., Swain, Geoffrey., Kavanagh, Christopher., Kovach, Brett., Schultz, Michael., Wiebe, Deborah., Holm, Eric., Montemarano, Jean., Wendt, Dean., Smith, Celia., Meyer, Anee.. Biofouling 2003, 19, 8794.
15. Stein, Judith., Truby, K., Wood, C. D., Stein, J., Gardner, M., Swain, G., Kavanagh, C., Kovach, B., Schultz, M., Wiebe, D., Holm, E., Montemarano, J., Wendt, D., Smith, C., Meyer, A.. Biofouling, 19, 7182 (2003).
16. Statz, A., Finlay, J.., Dalsin, J., Callow, M., Callow, J., Messersmith, P. B., Biofouling, 22, 391399 (2006).
17. Holland, R., Dugdale, T. M.., Wetherbee, R., Brennan, A. B., Finlay, J. A., Callow, J. A., Callow, M. E., Biofouling, 20, 323329 (2004).
18. Chaudhury, M., Finlay, J. A., Chung, J. Y., Callow, M. E., Callow, J. A., Biofouling, 21, 4148. (2005).
19. Jan, G.., Kirill, E., Biofouling, 22, 339360 (2006).
20. Kavanagh, C. J., Swain, G. W., Kovach, B. S., Stein, J., Wood, C. D., Truby, K., Holm, E., Montemarano, J., Meyer, A., D. Wiebe. Biofouling, 19, 381390 (2003).
21. Wendt, D. E., Kowalke, G. L., Kim, J., Singer, I. L., Biofouling, 22, 19 (2006).

Study of Oxetane Toughened Cationic UV Curable Marine Fouling Release Coating

  • Zhigang Chen (a1), Rachel Wagner (a1), Sandeep Patel (a1), Jongsoo Kim (a1), Shane Stafslien (a1), Justin Daniels (a1), Lyndsi Vander Wal (a1), Chavanin Siripirom (a2) and Bret Chisholm (a1)...

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 0 *
Loading metrics...

Abstract views

Total abstract views: 0 *
Loading metrics...

* Views captured on Cambridge Core between <date>. This data will be updated every 24 hours.

Usage data cannot currently be displayed