Hostname: page-component-8448b6f56d-cfpbc Total loading time: 0 Render date: 2024-04-24T01:18:05.258Z Has data issue: false hasContentIssue false
  • English
  • Français

The Structure of a Molybdenum Disulfide Intercalation Compound

Published online by Cambridge University Press:  01 February 2011

Ralf Brüning ,
Kristopher Bulmer ,
Rabin Bissessur ,
Robert I. Haines ,
Pravin Varma  and
Stephen Emeneau
Ralf Brüning
Affiliation:
Physics Department, Mount Allison University, Sackville, New Brunswick, Canada E4L 1E6
Kristopher Bulmer
Affiliation:
Physics Department, Mount Allison University, Sackville, New Brunswick, Canada E4L 1E6
Rabin Bissessur
Affiliation:
Department of Chemistry, University of Prince Edward Island, Charlottetown, Prince Edward Island, Canada C1A 4P3
Robert I. Haines
Affiliation:
Department of Chemistry, University of Prince Edward Island, Charlottetown, Prince Edward Island, Canada C1A 4P3
Pravin Varma
Affiliation:
Physics Department, Mount Allison University, Sackville, New Brunswick, Canada E4L 1E6
Stephen Emeneau
Affiliation:
Physics Department, Mount Allison University, Sackville, New Brunswick, Canada E4L 1E6
Get access

Abstract

The X-ray powder diffraction spectrum of MoS2 with intercalated 5, 5, 7, 12, 12, 14-hexamethyl-1, 4, 8, 11-tetraazacyclotetradecane-1-acetic acid shows well-defined peaks as well as broad scattering. The X-ray scattering of this compound was simulated by generating model particles and calculating their X-ray scattering by evaluating the Debye sum. The match between the measured and simulated spectra was improved by trial-and-error. Matching the peak widths shows that the particles contain a total of about 6600 MoS2 units in about eight layers. The layers are oriented in the same direction (not turbostratic). However, they are translated randomly in the plane perpendicular to the stacking direction. In contrast to prior work on intercalation compounds, which considered various types of periodic reconstruction within the MoS2 layer, we obtain the best match with a non-periodic reconstruction in addition to a periodic superlattice. It involves dimer and trimer groupings of the molybdenum atoms with a random choice of centers. The intercalated tetraazamacrocycles form a two-dimensional glass. The effects of the key model assumptions on the calculated spectrum are demonstrated.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 847: Symposium EE – Organic/Inorganic Hybrid Materials , 2004 , EE9.34
Copyright
Copyright © Materials Research Society 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Yang, D., Jiménez Sandoval, S., Divigalpitiya, W.M.R., Irwin, J.C. and Frindt, R.F., Phys. Rev. B 14, 12053 (1991).Google Scholar
2. Gordon, R.A., Yang, D., Crozier, E.D., Jiang, D.T. and Frindt, R.F., Phys. Rev. B 65, 125407 (2002).Google Scholar
3. Bissessur, R., Haines, R.I., Hutchings, D.R. and Brüning, R., Chem. Commun. 17, 1598 (2001).Google Scholar
4. Bissessur, R., Haines, R.I. and Brüning, R., J. Mater. Chem. 13, 44 (2003).Google Scholar
5. Hwang, S.-J., Petkov, V., Rangan, K.K., Shastri, S. and Kanatzidis, M.G., J. Phys. Chem. B 106, 12453 (2002).Google Scholar
6. Petkov, V., Billinge, S.J.L., Larson, P., Mahanti, S.D., Vogt, T., Rangan, K.K. and Kanatzidis, M.G., Phys. Rev. B. 65, 092105 (2002).Google Scholar
7. Heising, J. and Kanatzidis, M.G., J. Am. Chem. Soc. 121, 11720 (1999).Google Scholar
8. Westreich, P., Yang, D. and Frindt, R.F., Mat. Res. Soc. Symp. Proc. 661, KK8.17.1 (2001).Google Scholar