Skip to main content Accessibility help
×
Home

Structure Determination of Ba8CoRh6O21, a New Member of the 2H-Perovskite Related Oxides

  • H.-C. zur Loye (a1), M. D. Smith (a2), K. E. Stitzer (a2), A. El Abed and J. Darriet (a3)...

Abstract

Single crystals of Ba8CoRh6O21 were grown out of a potassium carbonate flux. The structure was solved by a general method using the superspace group approach. The superspace group employed was R3m(00γ)0s with a = 10.0431(1) Å, c1 = 2.5946(1) Å and c2 = 4.5405(1) Å, V = 226.60(1) Å3. Ba8CoRh6O21 represents the first example of an m = 5, n = 3 member of the A3n+3mA'nB3m+nO9m+6n family of 2H hexagonal perovskite related oxides and contains chains consisting of six consecutive RhO6 octahedra followed by one distorted CoO6 trigonal prism. These chains in turn are separated from each other by [Ba] chains.

Copyright

References

Hide All
1. Schlenker, C.; Dumas, J. Crystal Chemistry and Properties of Materials with Quasi-One- Dimensional Structures, A Chemical and Physical Approach; Rouxel, J. (ed), D. Reidel Publishing Co.: Boston 1986, p. 135.
2. de Jongh, L. J.; Miedema, A. R. Adv. Phys. 1974, 23, 1.
3. Day, P. Solid State Chemistry Compounds, Cheetham, A.K.; Day, P. (eds), Clarendon Press: Oxford 1992, Chp. 2.
4. Nguyen, T. N.; Giaquinta, D. M.; zur Loye, H.-C. Chem. Mater. 1994, 6, 1642.
5. Nguyen, T. N.; Lee, P. A.; zur Loye, H.-C. Science 1996, 271, 489.
6. Fjellvåg, H.; Gulbrandsen, E.; Aasland, S.; Olsen, A.; Hauback, B.C. J. Solid State Chem. 1996, 124, 190.
7. Kagayama, H.; Yoshima, K.; Kosuge, K.; Mitamura, H.; Goto, T. J. Phys. Soc. Jpn. 1997, 66, 1607.
8. Campá, J.A.; Gutiérrez-Puebla, E.; Monge, M.A.; Rasines, I.; Ruíz-Valero, C. J. Solid State Chem. 1994, 108, 203.
9. Harrison, W.T.A.; Hegwood, S.L.; Jacobson, A.J. J. Chem. Soc., Chem. Commun. 1995, 1953.
10. Battle, P.D.; Blake, G.R.; Darriet, J.; Gore, J.G.; Weill, F.G. J. Mater. Chem. 1997, 7, 1559.
11. Strunk, M.; Müller-Buschbaum, Hk. J. Alloys.Comp. 1994, 209, 189.
12. Dussarrat, C.; Fompeyrine, J.; Darriet, J. Eu. J. Solid State Inorg. Chem. 1995, 32, 3.
13. Campá, J.; Gutierrez-Puebla, E.; Monge, A.; Rasines, I.; Ruíz-Valero, C. J. Solid State Chem. 1996, 126, 27.
14. Layland, R. C.; Claridge, J. B.; Adams, R. D.; zur Loye, H.-C. Z. Anorg. Allg. Chem. 1997, 623, 1131.
15. Reisner, B. A.; Stacy, A. M. J. Am. Chem. Soc. 1998, 120, 9682.
16. Blake, G.R.; Sloan, J.; Vente, J.F.; Battle, P. D. Chem. Mater. 1998, 10, 3536.
17. Battle, P.D.; Blake, G.R.; Darriet, J.; Gore, J.G.; and Weill, F.G. J. Mater. Chem. 1997, 7, 1559.
18. Huvé, M.; Renard, C.; Abraham, F.; Van Tendeloo, G.; Amelinckx, S. J. Solid State Chem. 1998, 135, 1.
19. Boulahya, K.; Parras, M.; González-Calbet, J. M. J Solid State Chem. 1999, 142, 419.
20. Smith, M. D.; zur Loye, H.-C. Chem. Mater. 2000, 12, 2404.
21. Beauchamp, K. M.; Irons, S. H.; Sangrey, T. D.; Smith, M. D.; zur Loye, H.-C. Phys. Rev. B. 2000, 61, 11594.
22. Zakhour-Nakhl, M.; Claridge, J. B.; Darriet, J.; Weill, F.; zur Loye, H.-C.; Perez-Mato, J.-M. J. Am. Chem. Soc. 2000, 122, 1618.
23. Layland, R. C.; zur Loye, H.-C. J. Alloys Comp. 2000, 299, 118.
24. Layland, R. C.; Kirkland, S. L.; zur Loye, H.-C. J. Solid State Chem. 1998, 139, 79.
25. Smith, M. D.; zur Loye, H.-C. Chem. Mater. 1999, 11, 2984.
26. Darriet, J.; Subramanian, M. A. J. Mater. Chem. 1995, 5, 54.
27. Perez-Mato, J. M.; Zakhour-Nakhl, M.; Weill, F.; Darriet, J. J. Mater Chem. 1999, 9, 2795.
28. Evain, M.; Boucher, F.; Gourdon, O.; Petricek, V.; Dusek, M.; Bezdicka, P. Chem. Mater. 1998, 10, 3068.
29. Gourdon, O.; Petricek, V.; Dusek, M.; Bezdicka, P.; Durovic, S.; Gyepesova, D.; Evain, M. Acta Cryst. 1999, B55, 841
30. Claridge, J. B.; Layland, R. C.; Henley, W. H.; zur Loye, H.-C. Chem. Mater. 1999, 11, 1376.
31. Henley, W. H.; Claridge, J. B.; zur Loye, H.-C. J. Cryst. Growth 1999, 204, 122.
32. zur Loye, H.-C.; Layland, R. C.; Smith, M. D.; Claridge, J. B. J. Cryst. Growth 2000, 211, 452.
33. Van Smaalen, S. Phys. Rev. B 1991, 43, 11330.
34. Janner, A.; Janssen, T. Acta Crystallogr. A 1980, 36, 399.
35. Janner, A.; Janssen, T. Acta Crystallogr. A 1980, 36, 408.
36. Perez-Mato, J. M.; Madariaga, G.; Zuniga, F. J.; Garcia Arribas, A. Acta Crystallogr. A 1987, 43, 216.
37. Van Smaalen, S. Crystallogr. Rev. 1995, 4, 79.
38. Dusek, M.; Petricek, V.; Wunschel, M.; Dinnebier, R.E.; van Smaaleen, S. J. Appl. Cryst., Submitted.
39. zur Loye, H.-C.; Stitzer, K.E.; Smith, M.D.; El Abed, A.; Darriet, J. Chem Mater., Submitted.

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 0 *
Loading metrics...

Abstract views

Total abstract views: 0 *
Loading metrics...

* Views captured on Cambridge Core between <date>. This data will be updated every 24 hours.

Usage data cannot currently be displayed