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The Structure and Ionic Conduction in Fluorite-Type Solid Solutions

  • Yoshiaki Ito (a1)

Abstract

The crystal structure of β-Pb0.9Bi0.1F2.1 has been investigated in the temperature range 294 to 710K by single crystal X-ray diffraction method. Phase transition is observed at about 700K and the mean square displacements (MSD) of metal and fluorine ions show a rapid increase near the transition temperature. The fluorine ions do not show anharmonic thermal vibrations in the regular site in the temperature range.

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1. Gillan, M. J. and Richardson, D. D., J. Phys.C. 12, L61 (1979).
2. lto, Y., Koto, K., Yoshikado, S., Ohachi, T., Kanamaru, F., and Mukoyama, T., J. Solid State Chem. 95, 94 (1991).
3. Bachmann, R. and Schulz, H., Solid State lonics, 9/10, 521 (1983).
4. Dickens, M. H., Hayes, W., Hutchings, M. H., and Smith, C., J. Phys. C. 15, 4043 (1982).
5. Samara, G. A., J. Phys. Chem. Solids 40, 509 (1979).
6. Schoonman, J. and Wappenaar, K. E. D., J. Electrochem. Soc. 128, 1385 (1979).
7. Liang, C.C. and Joshi, A.V., J.Electrochem. Soc. 122, 465 (1975).
8 Kennedy, J. H. and Miles, R., J. Electrochem. Soc. 123, 47 (1977).
9. Lucat, C., Campet, G., Claverie, J., Portier, J., Reau, J. M., and Hagenmilller, P., Mat. Res. Bull. 11, 167 (1976).
10. Lucat, C., Portier, J., Reau, J. M., Hagenmiiller, P., and Soubeyroux, J. L., J. Solid State Chem. 32, 279 (1980).
11. Reau, J. M., Fedorov, P. P., Rabardel, L., Matar, S. F., and Hagenmiiller, P., Mat. Res. Bull. 18, 1235 (1983).
12. Ito, Y., Koto, K., Yoshikado, S., Ohachi, T., Solid State Ionics, 18/19, 1202 (1986).
13. Ibers, J. A. and Hamilton, W. C., International Tables for X-ray Crystallography, Vol. IV. (Kluwer Academic Publishers, Holland, 1989), pp.99-101 and pp. 149150.
14. Finger, L. W., RFINE, a Fortran IV computer program for structure factor calculation and least squares refinement of crystal structures. Geophys. Lab., Carnegie Inst. of Washington, Washington DC (1972).

The Structure and Ionic Conduction in Fluorite-Type Solid Solutions

  • Yoshiaki Ito (a1)

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