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Stacking Faults and Dislocation Dissociation in MoSi2

Published online by Cambridge University Press:  21 September 2018

Miroslav Cak ,
Mojmir Sob ,
Vaclav Paidar  and
Vaclav Vitek
Miroslav Cak
Affiliation:
Department of Materials Science and Engineering, University of Pennsylvania, 3231 Walnut Street, Philadelphia, PA 19104, USA Institute of Physics of Materials, Academy of Sciences of the Czech Republic, CZ-616 62 Brno, Czech Republic
Mojmir Sob
Affiliation:
Institute of Physics of Materials, Academy of Sciences of the Czech Republic, CZ-616 62 Brno, Czech Republic Department of Chemistry, Faculty of Science, Masaryk University, CZ-611 37 Brno, Czech Republic
Vaclav Paidar
Affiliation:
Institute of Physics, Academy of Sciences of the Czech Republic, CZ-182 21 Praha 8, Czech Republic
Vaclav Vitek
Affiliation:
Department of Materials Science and Engineering, University of Pennsylvania, 3231 Walnut Street, Philadelphia, PA 19104, USA
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Abstract

The intermetallic compound MoSi2 crystallises in the body-centred-tetragonal C11b structure and while it is brittle when loaded in tension, it deforms plastically in compression even at and below the room temperature. The ductility of MoSi2 is controlled by the mobility of 1/2〈331] dislocations on {013) planes but the critical resolved shear stress for this slip system depends strongly on the orientation of loading and it is the highest for compression along the 〈001] axis. Such deformation behaviour suggests that the dislocation core is controlling the slip on the {013)〈331] system. Since the most important core effect is dissociation into partial dislocations connected by metastable stacking faults the first goal of this paper is to ascertain such faults. This is done by employing the concept of the γ-surface. The γ-surfaces have been calculated for the (013) and (110) planes using a method based on the density functional theory. While there is only one possible stacking fault on the (110) plane, three distinct stacking faults have been found on the (013) plane. This leads to a variety of possible dislocation splittings and the energetics of these dissociations has been studied by employing the anisotropic elastic theory of dislocations. The most important finding is the non-planar dissociation of the 1/2〈331] screw dislocation that is favoured over the planar splittings and may be responsible for the orientation dependence of the critical resolved shear stress for the {013)〈331] slip system.

Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1128: Symposium U – Advanced Intermetallic-Based Alloys for Extreme Environment and Energy Applications , 2008 , 1128-U07-10
Copyright
Copyright © Materials Research Society 2009

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References

1. Dimiduk, D. M. and Perepezko, J. H., MRS Bull 28, 639 (2003).Google Scholar
2. Sharif, A. A., Misra, A. and Mitchell, T. E., Scripta Mater. 52, 399 (2005).Google Scholar
3. Ito, K., Inui, H., Shirai, Y. and Yamaguchi, M., Philos. Mag. A 72, 1075 (1995).Google Scholar
4. Ito, K., Yano, H., Inui, H. and Yamaguchi, M. in High-Temperature Ordered Intermetallic Alloys VI, edited by Horton, J. A., Baker, I., Hanada, S., Noebe, R. D. and Schwartz, D. S. (Pittsburgh, Materials Research Society), Vol. 364, p. 899 (1995).Google Scholar
5. Ito, K., Matsuda, K., Shirai, Y., Inui, H. and Yamaguchi, M., Mat. Sci. Eng. A 261, 99 (1999).Google Scholar
6. Messerschmidt, U., Guder, S., Junker, L., Bartsch, M. and Yamaguchi, M., Mater. Sci. Eng. A 319, 342 (2001).Google Scholar
7. Dietzsch, C., Bartsch, M. and Messerschmidt, U., Phys Stat. Sol. A 202, 2249 (2005).Google Scholar
8. Villars, P. and Calvert, L. D., Pearson's Handbook of Crystallographic Data for Intermetallic Phases, (ASM, Metals Park, OH, 1985).Google Scholar
9. Inui, H., Nakamoto, T., Ishikawa, K. and Yamaguchi, M., Mat. Sci. Eng. A 261, 131 (1999).Google Scholar
10. Rao, S. I., Dimiduk, D. M. and Mendiratta, M. G., Philos. Mag. A 68, 1295 (1993).Google Scholar
11. Duesbery, M. S. in Dislocations in Solids, edited by Nabarro, F. R. N. (Amsterdam, Elsevier), Vol. 8, p. 67 (1989).Google Scholar
12. Vitek, V. in Handbook of Materials Modeling Part B: Models, edited by Yip, S. (New York, Springer), p. 2883 (2005).Google Scholar
13. Vitek, V. and Paidar, V. in Dislocations in Solids, edited by Hirth, J. P. (Amsterdam, Elsevier), Vol. 14, p. 439 (2008).Google Scholar
14. Vitek, V., Philos. Mag. A 18, 773 (1968).Google Scholar
15. Kresse, G. and Hafner, J., Phys. Rev. B 47, 558 (1993).Google Scholar
16. Kresse, G. and Furthmüller, J., Comp. Mat. Sci. 6, 15 (1996).Google Scholar
17. Waghmare, U. V., Bulatov, V., Kaxiras, E. and Duesbery, M. S., Philos. Mag. A 79, 655 (1999).Google Scholar
18. Mitchell, T. E., Baskes, M. I., Chen, S. P., Hirth, J. P. and Hoagland, R. G., Philos. Mag. A 81, 1079 (2001).Google Scholar
19. Hirth, J. P. and Lothe, J., Theory of Dislocations, (Wiley-Interscience, New York, 1982).Google Scholar
20. Mitchell, T. E., Baskes, M. I., Hoagland, R. G. and Misra, A., Intermetallics 9, 849 (2001).Google Scholar
21. Cottrell, A. H., Philos. Mag. 43, 645 (1952).Google Scholar
22. Paidar, V. and Vitek, V. in Intermetallic Compouds: Principles and Practice, edited by Westbrook, J. H. and Fleisher, R. L. (New York, John Wiley), Vol. 3, p. 437 (2002).Google Scholar