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Self-Assembled Organic Monolayer Films on Underpotentially Deposited Metal Layers

Published online by Cambridge University Press:  10 February 2011

G. K. Jennings  and
P. E. Laibinis
G. K. Jennings
Affiliation:
Dept. of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139
P. E. Laibinis
Affiliation:
Dept. of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139
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Abstract

This paper describes a new family of organized molecular assemblies that are produced by the spontaneous adsorption of alkanethiols onto gold surfaces that have been modified by the underpotential deposition of copper or silver. The system has the flexibility associated with the formation of self-assembled monolayers by the adsorption of thiols onto gold with the advantage of improved stability. The use of these systems as modified electrodes is also addressed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 451: Symposium P – Electrochemical Synthesis and Modification , 1996 , 155
Copyright
Copyright © Materials Research Society 1997

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References

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