Skip to main content Accessibility help
×
Home

Raman and Photoluminescence Spectroscopic Study of 1-Undecene Functionalized Nanodiamonds

  • Y. Astuti (a1) (a2), N. R. J. Poolton (a3) and L. Šiller (a1)

Abstract

Nanodiamond holds great interest in a variety of optical applications, the properties being correlated with surface modification, and the presence of both impurities and defects (contained either on their surface or within the crystal structure). Undecyl-nanodiamond produced by attachment of 1-undecene onto the nanodiamond surface could be a good candidate as a luminescent marker in the future; therefore, understanding of its optical properties is essential. In this work, the optical properties of the acid-purified nanodiamond and undecyl-nanodiamond were characterised using surface enhanced Raman spectroscopy (SERS) and photoluminescence spectroscopy. The results demonstrate that the characteristic diamond Raman signal at 1330 cm-1 was still observed after chemical surface modification, while the signal at ∼1600 cm-1 (attributed to graphite bands) disappeared after the modification. Broad photoluminescence emission is detected in the range 1.5-2.5 eV (500-800 nm), as typically found for isolated nanodiamond; these emission bands became narrower with attachment of 1-undecene as compared to the sample without surface functionalisation. The observed emission could be related to structural disorder on the nanodiamond surface. The temperature dependence of the intensity, peak position and band widths of each sample has been characterised.

Copyright

References

Hide All
1. Shenderova, O.A., Gruen, D.M., Ultrananocrystalline Diamond, William Andrew Publishing, Norwich, New York, 2006.
2. Krueger, A., J. Mater. Chem. 21, 1257112578 (2011).
3. Schrand, A.M., Hens, S.A.C. & Shenderova, O.A., Crit. Rev. Solid State Mater. Sci. 34, 1874 (2009).
4. Mochalin, V. N., Gogotsi, Y., J. Am. Chem. Soc. 131, 45944595 (2009).
5. Astuti, Y., Butenko, Y. V., Alves, L., van Papendrecht, G., Bangert, U., Gass, M., Mendis, B. and Šiller, L., Manuscript: Deaglomeration and evaporation of nanodiamonds, submitted .
6. Šiller, L., Butenko, Y.V., Method for the separation of diamond particle clusters, UK patent application no. GB 1207327.6, filling date 27th April 2012.
7. Link, S., Wang, Z.L., El-Sayed, M.A., J. Phys. Chem. B 103, 35293533 (1999).
8. Poolton, N. R. J., Bos, A. J. J., Wallinga, J., De Haas, J. T. M., Dorenbos, P., De Vries, L., Kars, R. H., Jones, G. O., Drozdowski, W., J. Lumin. 130, 14041414 (2010).
9. Liu, Y. L., Sun, K. W., Nanoscale Res. Lett. 5, 10451050 (2010).
10. Mochalin, V., Osswald, S., Gogotsi, Y., Chem. Mater. 21, 273279 (2009).
11. Lueking, A., Gutierrez, H., Narayanan, D., Clifford, C. E. B., Jain, P. (2010) Lower pressure synthesis of diamond material. US 7,754,179 B2 23 (Patent).
12. Lopez-Rios, T., Sandre, E., Leclercq, S., Sauvain, E., Phys. Rev. Lett. 76, 49354938 (1996).
13. Tobin, M. C., Laser Raman Spectroscopy, Wiley-Interscience, New York, 1971.
14. Ferrari, A.C., Robertson, J., Phys. Rev. B 63, 12140511214054 (2001).
15. Vandenabeele, P., Wehling, B., Moens, L., Edwards, H., De Reu, M., Van Hooydonk, G., Anal. Chim. Acta 407, 261274 (2000).
16. Inagaki, F., Tasumi, M., Miyazawa, T., J. Raman Spectrosc. 3 335343 (1975).
17. Naylor, C. C., Meier, R. J., Kip, B. J., Williams, K. P. J., Mason, S. M., Conroy, N., Gerrard, D. L., Macromolecules 28, 29692978 (1995).
18. Vlasov, I. I., Shenderova, O. A., Turner, S., Lebedev, O. I., Basov, A. A., Sildos, I., Rahn, M., Shiryaev, A. A., Van Tendeloo, G., Small 6, 687694 (2010).
19. Keblinski, P., Wolf, D., Cleri, F., Phillpot, S.R., Gleiter, H., MRS Bulletin 23, 3641 (1998).
20. Hirai, H., Terauchi, M., Tanaka, M., Kondo, K., Diam. Relat. Mater 8, 17031706 ((1999).
21. Kompan, M., Terukov, E., Gordeev, S., Zhukov, S., Nikolaev, Y., Phys. Solid State 39, 19281929 (1997).
22. Catledge, S.A., Singh, S., Adv. Sci. Lett. 4, 512515 (2011).

Keywords

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 0 *
Loading metrics...

Abstract views

Total abstract views: 0 *
Loading metrics...

* Views captured on Cambridge Core between <date>. This data will be updated every 24 hours.

Usage data cannot currently be displayed