Hostname: page-component-8448b6f56d-qsmjn Total loading time: 0 Render date: 2024-04-24T04:33:30.878Z Has data issue: false hasContentIssue false
  • English
  • Français

Preparation of Non-Oxide Ceramics by Pyrolysis of Organometallic Precursors

Published online by Cambridge University Press:  25 February 2011

Leonard V. Interrante ,
Wayde R Schmidt ,
Paul S. Marchetti  and
Gary E. Maciel
Leonard V. Interrante
Affiliation:
Department of Chemistry, Rensselaer Polytechnic Institute, Troy, NY 12180–3590
Wayde R Schmidt
Affiliation:
Department of Chemistry, Rensselaer Polytechnic Institute, Troy, NY 12180–3590
Paul S. Marchetti
Affiliation:
Department of Chemistry, Colorado State University, Fort Collins, CO 80523.
Gary E. Maciel
Affiliation:
Department of Chemistry, Colorado State University, Fort Collins, CO 80523.
Get access

Extract

Chemical processing routes to advanced ceramic materials are gaining importance as a convenient approach to control the stoichiometry, purity, microstructure and final form of the ceramic products [1]. The pyrolytic conversion of organometallic molecules and polymers is one such chemical processing route that has been widely applied in ceramic fiber technology [1,2], in coating processes [1,2], and in the sintering of bulk ceramic objects [3]. Despite these advances in practical applications, there is a continuing need in this area for a better fundamental understanding of the chemistry involved during the precursor-to-ceramic conversion process and for the development of new precursors which yield the desired ceramic(s) in high yield and purity.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 271: Symposium N – Better Ceramics Through Chemistry V , 1992 , 739
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. a) Wynne, K. J. and Rice, R. W., Annu. Rev. Mater. Sci., 14 (1984) 297;Google Scholar
b) Ulrich, D. R., “Chemical Processing of Ceramics” Chemical and Engineering News, Jan. 1 (1990) 28;Google Scholar
c) Segal, D., Chemical Synthesis of Advanced Ceramic Materials, Cambridge University Press: New York, (1989).CrossRefGoogle Scholar
2. Fischer, H. E., Larkin, D. J., and Interrante, L. V., MRS Bull., 26 [4] (1991) 59–65;Google Scholar
b) Cooke, T. F., J. Am. Ceram. Soc., 74 [12] (1991) 2959.Google Scholar
3. a) Schwab, S. T. and Blanchard-Ardid, C. R., Mat. Res. Soc. Symp. Proc., 121 (1988) 581;Google Scholar
b) Atwell, W. H., Burns, G. T., and Zank, G. A., “Silicon Carbide Preceramic Polymers as Binders for Ceramic Powders” in Inorganic and Orpanometallic Oligomers and Polymers. Harrod, J. F. and Laine, R. M., eds., Kluwer Academic Publishers, (1991) 147–159.Google Scholar
4. Wakai, F., Kodama, Y., Sakaguchi, S., Murayama, N., Iraki, K., and Niihara, K., Nature, 344 [29 March] (1990) 421.Google Scholar
5. a) Maehara, Y. and Langdon, T. G., J. Mat. Sci., 25 (1990) 2275;CrossRefGoogle Scholar
b) Chen, I. -W. and Xue, L. A., J. Am. Ceram. Soc., 73[9] (1990) 2585;Google Scholar
b) Siegel, R. W., MRS Bull., 25[10] (1990) 60.Google Scholar
6. a) Chorley, R. W. and Lednor, P. W., Adv. Mater., 3[10] (1991) 474;CrossRefGoogle Scholar
b) Yamanaka, S., Ceram. Bull., 70[6] (1991) 1056.Google Scholar
7. Interrante, L. V., Carpenter, L. E. II, Whitmarsh, C., and Lee, W., Mat. Res. Soc. Symp. Proc., 73 (1986) 359.Google Scholar
8. Interrante, L. V., Lee, W., McConnell, M., Lewis, N. and Hall, E., J. Electrochem. Soc., 1360[2] (1989) 472–478.Google Scholar
9. Sauls, F. C., Interrante, L. V. and Jiang, Z., Inorg. Chem., 29 (1990) 2989–96.Google Scholar
10. Sauls, F. C., Czekaj, C. L., and Interrante, L. V., Inorg. Chem., 29[23] (1990) 4688–4692.Google Scholar
11. a) Interrante, L. V., Sigel, G. A., Hejna, C. and Garbauskas, M., Inorg. Chem., 28 (1989) 252–257;CrossRefGoogle Scholar
b) Interrante, L. V., Sigel, G. A., Hejna, C. and Garbauskas, M., Phosphorus, Sulfur and Silicon, 41 (1989) 325–334.Google Scholar
12. Lynam, M. M., Interrante, L. V., Patterson, C. H., and Messmer, R. P., Inorg. Chem., 30 (1991) 1918–1922.CrossRefGoogle Scholar
13. a) Amato, C. C., Hudson, J. B. and Interrante, L. V., Mat. Res. Soc. Symp. Proc., 168 (1990) 119–124;Google Scholar
b) Amato, C. C., Hudson, J. B., and Interrante, L. V., Mat. Res. Soc. Symp. Proc., 204 (1991) 135–140.Google Scholar
14. Jiang, Z. and Interrante, L. V., Chem. Mater., 2 (1990) 439–446.Google Scholar
15. Jiang, Z., Interrante, L. V., Kwon, D., Tham, F. S., and Kullnig, R., Inorg. Chem., 30 (1991) 995–1000.CrossRefGoogle Scholar
16. a) Pysher, D. J., Goretta, K. C., Hodder, R. S. Jr, and Tressler, R. E., J. Am. Ceram. Soc., 72[2] (1988) 244;Google Scholar
b) Zhang, Z. -F., Babonneau, F., Laine, R. M., Mu, Y., Harrod, J. F., and Rahn, J. A., J. Am. Ceram. Soc., 74[3] (1991) 1670.Google Scholar
17. Whitmarsh, C. and Interrante, L. V., Organometallics, 10 (1991) 1336–1344.Google Scholar
18. Yang, C. -Y. and Interrante, L. V.,“Thermally and Chemically Induced Crosslinking of a Hydridopolycarbosilane for Optimization of Silicon Carbide Yield” submitted to Polymer Preprints. Google Scholar
19. Interrante, L. V., Whitmarsh, C. K., Trout, T. K., and Schmidt, W. R., “Synthesis and Pyrolysis Chemistry of Polymeric Precursors to SiC and Si3N4 ” Kluwer Academic Publishers, Dordrecht, (1991); Proceedings. NATO Workshop on Organometallic Polymers with Special Properties. Cap D'Agde, France, Sept. 10–15, 1990.Google Scholar
20. a) Wu, H. -J. and Interrante, L. V., “Preparation of A Linear Polycarbosilane via Ring-Opening Polymerization” Polymer Preprints, 4th Chem. Congress, NY, Aug. 1991;Google Scholar
b) Wu, H.-J. and Interrante, L. V., Macromolecule, 25 (1992) 1840.Google Scholar
21. Schmidt, W. R., Interrante, L. V., Doremus, R. H., Trout, T. K., Marchetti, P. S., and Maciel, G. E., Chem. Mater., 3 [2] (1991) 257–267.Google Scholar
22. Schmidt, W. R., Sukumar, V., Hurley, W. J. Jr, Garcia, R., Doremus, R. H., and Interrante, L. V., J. Am. Ceram. Soc., 73[8] (1990) 2412.Google Scholar
23. Sukumar, V., Schmidt, W. R., Garcia, R., Doremus, R. H. and Interrante, L. V., Mater. Letters, 9 (1990) 117–120.Google Scholar
24. Schmidt, W. R., Marchetti, P. S., Interrante, L. V., Hurley, W. J. Jr, Lewis, R. H., Doremus, R. H., and Maciel, G. E., “Ammonia-Induced Pyrolytic Conversion of a Vinylic Polysilane to Silicon Nitride” submitted to Chem. Mater,Google Scholar
25. Narsavage, D. M., Interrante, L. V., Marchetti, P. S., and Maciel, G. E., Chem. Mater., 3[4] (1991) 721.Google Scholar
26. a) Czekaj, C. L., Hackney, M. L., Hurley, W. J. Jr, Interrante, L. V. and Sigel, G. A., J. Am. Ceram. Soc., 73[2] (1990) 352–357;Google Scholar
b) Interrante, L. V., Schmidt, W. R., Shaikh, S. N., Garcia, R., Marchetti, P. S., and Maciel, G., “Silicon Carbide Aluminum Nitride Solid Solutions by Pyrolysis of Organometallics” Proc. 5th Intl. Conf on Ultrastructure Processing of Ceramics. Glasses. Composites. Ordered Polymers and Advanced Optical Materials. Series E: Applied Sciences, Vol. 206, J. Wiley and Sons, publs., (1991) 243–254.Google Scholar
27. a) Zangvil, A. and Ruh, R., J. Am. Ceram. Soc., 71[10] (1988) 884;Google Scholar
b) Ruh, R. and Zangvil, A., J. Am. Ceram. Soc., 65[5] (1982) 260;Google Scholar
c) Rafaniello, W., Plichta, M. R., and Virkar, A. V., J. Am. Ceram. Soc., 66[4] (1983) 272;CrossRefGoogle Scholar
d) Rafaniello, W., Cho, K., and Virkar, A. V., J. Mater. Sci., 16[12] (1981) 3479.Google Scholar
28. Ervin, G. Jr, US Patent 3,492,153, Jan. 27, 1970.Google Scholar
29. a) Kwon, D., Schmidt, W. R., Interrante, L. V., Marchetti, P., and Maciel, G., “Preparation and Microstructure of Organometallic Polymer Derived AlN-BN Composites” Inorganic and Organometallic Oligomers and Polymers, Harrod, J. F. and Laine, R. M., eds., Kluwer Academic Publishers, (1991) 191–197;Google Scholar
b) Schmidt, W. R., Hurley, W. J. Jr, Sukumar, V., Doremus, R. H., and Interrante, L. V., Mat. Res. Soc. Symp. Proc, 171 (1990) 79–84;Google Scholar
c) Interrante, L. V., Hurley, W. J. Jr, Schmidt, W. R., Kwon, D., Doremus, R. H., Marchetti, P. S., and Maciel, G., “Preparation of Nanocrystalline Composites by Pyrolysis of Organometallic Precursors” Proceedings, Symposium on Composites, American Ceramic Society Meeting, Orlando, FL, Nov. 1990,Google Scholar
Advanced Composite Materials-Ceramic Transactions. Vol. 19, Sacks, M. D., ed. American Ceramic Society: Westerville, Ohio, (1991) 3–17;Google Scholar
d) Schmidt, W. R., Hurley, W. J. Jr, Doremus, R. H., Interrante, L. V., and Marchetti, P. S., “Novel Polymer Precursors to Si-C-Al-O-N Ceramic Composites” Proceedings, Symposium on Composites, American Ceramic Society Meeting, Orlando, FL, Nov. 1990, Advanced Composite Materials-Ceramic Transactions. Vol. 19, Sacks, M. D., ed. American Ceramic Society, Westerville: Ohio, (1991) 19–25.Google Scholar