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Preparation of Amazingly Hard polyHIPE material from a Direct Emulsion

  • Carlos Youssef (a1), Rénal Backov (a2), Mona Treguer (a3), Marc Birot (a4) and Hervé Deleuze (a5)...

Abstract

Interconnected microcellular polymeric monoliths having unexpected high mechanical strength have been prepared using the High Internal Phase Emulsion methodology. Direct concentrated emulsions of aqueous 5-amino-1-vinyl-[1,2,3,4]tetrazole mixed with low molar (5 %) fractions of N,N'-methylenebisacrylamide (MBA) as cross-linking agent were prepared using dodecane as dispersed phase and a mixture of hydrophilic surfactants. “Reverse” polyHIPE materials were obtained after radical copolymerization, solvent extraction and drying. Their morphology, chemical composition and physico-chemical behaviour are discussed.

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1 Barby, D.; Haq, Z. Eur. Pat. 60, 138, 1982.
2 Lissant, K. J. in Emulsions and Emulsions Technology Part 1, Marcel Dekker Inc., New York, 1974.
3 Taylor, S. P. Rec. Res. Devel. Surf. Col. 2004, 1, 183.
4 Menner, A.; Powell, R.; Bismarck, A. Macromolecules 2006, 39, 2034.
5 Cameron, N. R.; Sherrington, D. C. Adv. Polym. Sci. 1996, 126, 163.
6 Silverstein, M. S.; Tai, H. W.; Sergienko, A.; Lumelsky, Y. L. L.; Pavlovsky, S.; Polymer 2005, 46, 6682.
7 Akay, G.; Birch, M. A.; Bohkhari, M. A. Biomaterials 2004, 25, 3991.
8 Krajnc, P.; Brown, J. F.; Cameron, N. R. Org. Lett. 2002, 4, 2497.
9 Menner, A.; Ikem, V.; Salgueiro, M.; Shaffer, , M. S. P., ; Bismarck, , A. Chem. Commun. 2007, 4274.
10 Lucchesi, C.; Pascual, S.; Dujardin, G.; Fontaine, , L. React. Funct. Polym. 2008, 68, 97.
11 Williams, J. M.; Wrobleski, D. A. Langmuir 1988, 4, 656.
12 Williams, J. M.; Gray, A. J.; Wilkerson, M. H. Langmuir 1990, 6, 437.
13 Akay, G.; Bhumgara, Z.; Wakeman, R. J. Chem. Eng. Res. Dev. 1995, 73, 782.
14 Barbetta, A.; Cameron, N. R.; Cooper, S. J Chem. Commun. 2000, 221.
15 Barbetta, A.; N. R., Cameron Macromolecules 2004, 37, 3188.
16 Barbetta, A.; N. R., Cameron Macromolecules 2004, 37, 3202.
17 Tai, H.; Sergienko, A.; Silverstein, M. S. Polym. Eng. Sci. 2001, 41, 1540.
18 Normatov, J.; Silverstein, M. S. Macromolecules 2007, 40, 8329.
19 Menner, A.; Powell, R.; Bismarck, A. Soft Mat. 2006, 4, 337.
20 Leber, N.; Fay, J. D. B.; Cameron, N. R.; Krajnc, P. J. Polym. Sci. A Polym. Chem. 2007, 45, 4043.
21 Junkar, I.; Koloini, T.; Krajnc, P.; Nemec, D.; Podgornik, A.; Strancar, A. J. Chromatogr. A. 2007, 1144, 48.
22 Krajnc, P.; Stefanec, D.; Pulko, I. Macromol. Rapid Comm. 2005, 26, 1289.
23 Ko, Y. C.; Lindsay, J. D. World Pa Pat. t. 044, 041, 2004.
24 Barbetta, A.; Dentini, M.; Zannoni, E. M.; M., De Stefano Langmuir 2005, 21, 12333.
25 Barbetta, A.; Dentini, M.; De Vecci, M. S.; Filippini, P.; Formisano, G.; Caiazza, S. Adv. Funct. Mat. 2005, 15, 118.
26 Duke, J. R.; Hoisington, M. A.; La Langlois, D. A.; , Benicewicz, nglois, B. C., Polymer 1998, 39, 4369.
27 Cameron, N. R.; Sherrington, D. C. Macromolecules 1997, 30, 5860
28 Lëpine, O.; Birot, M.; Deleuze, H. Macro. Mat. Eng. 2009, 294, 599
29 Lëpine, O.; Deleuze, H. Coll. Polym. Sci. 2008, 286, 1273
30 Audouin, F.; Birot, M.; Pasquinet, E.; Deleuze, H.; Besnard, O.; Poullain, D. J. Appl. Polym. Chem. 2008, 108, 2808
31 Grosse, M Birot, M-T., Lamotte, M., M., ; Deleuze, H. J. Polym. Sci. A Polym. Chem. 2008, 46, 21
32 Lëpine, O.; Birot, M.; Deleuze, H. J. Polym. Sci. A Polym. Chem. 2007, 45, 4193
33 Barmin, M. I.; Gromava, S. A.; Mel'nikov, V. V. Russ. J. Appl. Chem. 2001, 74, 1156.
34 Arnold, C.; Thatcher, D. N. J. Org. Chem. 1969, 34, 1141.
35 Besnard, O.; Pasquinet, E.; Birot, M.; Deleuze, H.; Audouin, F. Fr. Pat. 08 53809, 2008.
36 Menner, A.; Salgueiro, M.; Shaffer, M. S. P.; Bismark, A., J. Polym. Sci., Part A Polym. Chem. 2008, 46, 5708.
37 Ermakova, T. G.; Kuznetsova, N. P.; Tatarova, L. A.; Lopyrev, V. A. Russ. J. Gen. Chem. 2007, 77, 132.

Keywords

Preparation of Amazingly Hard polyHIPE material from a Direct Emulsion

  • Carlos Youssef (a1), Rénal Backov (a2), Mona Treguer (a3), Marc Birot (a4) and Hervé Deleuze (a5)...

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