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Preparation and Properties of Inorganic-Organic Hybrids From Vinyland 3-Methacryloxypropyltrimethoxysilane

  • N. Takamura (a1), T. Gunji (a1) and Y. Abe (a1)


The organic-inorganic polymer hybrids consisting of carbon-carbon and siloxane chains were prepared by radical polymerization of vinyltrimethoxysilane (VTS) and 3-methacryloxypropyltrimethoxysilane (MAS) followed by hydrolytic polycondensation. Polyvinyltrimethoxysilane (PVTS) and poly(3-methacryloxypropyltrimethoxysilane) (S-PMA) with various molecular weights Mw=3900–64800 were prepared by polyaddition of VTS and MAS, respectively. PVTS and S-PMA provided transparent and flexible free-standing films and coating films. With increasing carbon-carbon chain length, the elasticity of the films increased, while the tensile strength and Young's modulus decreased. The adhesive strength of the coating films on organic substrates was particularly dependent on the solubility parameter, polarity and crystallinity of each substrate. The pencil-hardness of coating films was clearly increased with increasing degree of condensation of sila-functional group in PVTS and S-PMA.



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1. Laine, R. M., Rahn, J. A., Youngddahl, K. A., Babonneau, F., Hoppe, M. L, Zhang, Z. F., and Harrod, J. F., Chem. Mater., 2, p. 464 (1990).10.1021/cm00010a028
2. Sellinger, A. and Laine, R. M., Polym. Prepr. 35, p. 665 (1994).
3. Abe, Y., Taguchi, K., Hatano, H., Gunji, T., Nagao, Y., and Misono, T., J. Sol-Gel Sci. Technol., 2, p.131 (1994).10.1007/BF00486226
4. Hoebbel, D., Endres, K., Reinert, T. and Pitsch, I., J. Non-Crystal. Solids, 174, p. 179 (1994).10.1016/0022-3093(94)90076-0
5. Zhang, Z., Tanigami, Y., and Terai, R., J. Non-Crystal. Solids, 191, p. 304 (1995).10.1016/0022-3093(95)00316-9
6. Baney, R. H., Itoh, M., Sakakibara, A., and Suzuki, T., Chem. Revs., p. 1409 (1995).10.1021/cr00037a012
7. Joseph, R., Zhang, S., and Ford, W. T., Macromolecules, 29, p. 1305 (1996).10.1021/ma951111z
8. Millar, J. R., J. Chem. Soc., 121, p. 1311 (1960).10.1039/JR9600001311
9. Schmidt, H., and Wolter, H., J. Non-Crystal. Solids 121, p. 428 (1990).10.1016/0022-3093(90)90171-H
10. Ellsworth, M. W. and Novak, B. M., Chem. Mater., 5, p. 839 (1993).10.1021/cm00030a020
11. Novak, B. M., Auerbach, D. and Verrier, C., Chem. Mater., 6, p. 282 (1994).10.1021/cm00039a006
12. Otsu, T., Endo, K., and Tanaka, M. Mem. Fac. Eng., Osaka City Univ., 29, p. 151 (1988).
13. Stober, M. R., Michael, K. W., and Speier, J. L., J. Org. Chem., 32, p. 2740 (1967).10.1021/jo01284a021
14. Bajaj, P., Khanna, Y. P., and Babu, G. N., J. Polym. Sci. Polym. Chem. Ed., 14, p. 465 (1975).10.1002/pol.1976.170140217
15. Billingham, N. C., Jenkins, A. D., Karonfli, E. B., and Walton, D. R. M., J. Polym. Sci. Polym. Chem. Ed., 16, p. 683 (1977).10.1002/pol.1977.170150315
16. Babu, G. N., Atodaria, D. R., and Deshpande, A., Eur. Polym. J., 17, p. 427 (1981).10.1016/0014-3057(81)90148-8
17. Bajaj, P., and Nanababu, G., Eur. Polym. J., 12, p. 601 (1976).10.1016/0014-3057(76)90023-9
18. Magner, G. H., Bailey, D. L., Pines, A. N., Bunham, M. L., and Mclntiare, D. B., Ind. Eng. Chem., 45, p. 367 (1953).
19. Mixer, P. Y. and Bailey, D. L., J. Polym. Sci., 18, p. 573 (1995).10.1002/pol.1955.120189013
20. Young, L. J., J. Polym. Sci., 54, p. 411 (1961).10.1002/pol.1961.1205416011
21. Scott, C. E. and Proce, C. C., J. Am. Chem. Soc., 81, p. 2670 (1959).10.1021/ja01520a019
22. Bailey, D. L., J. Polym. Sci., 22, p. 55 (1956).
23. Sakurai, H., Tominaga, K., and Kumada, M., Bull. Chem. Soc. Jpn., 39, p. 1279 (1966).10.1246/bcsj.39.1279
24. Kendall, K., J. Phys. D, 4, p. 1186(1971).10.1088/0022-3727/4/8/320
25. Abe, Y., Honda, Y., and Gunji, T., Appl. Organometal. Chem., 12, p. 1 (1998).10.1002/(SICI)1099-0739(199810/11)12:10/11<749::AID-AOC782>3.0.CO;2-2
26. Fedors, R. F., Polym. Eng. Sci., 14, p. 147 (1974).10.1002/pen.760140211

Preparation and Properties of Inorganic-Organic Hybrids From Vinyland 3-Methacryloxypropyltrimethoxysilane

  • N. Takamura (a1), T. Gunji (a1) and Y. Abe (a1)


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