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Preparation and Processing of Monodisperse Colloidal Silica-Cadmium sulfide nanocomposites

  • Song-Yuan Chang (a1), Lei Liu (a1) and Sanford A. Asher (a1)

Abstract

A novel synthetic methodology has been developed for preparing monodisperse colloidal silica-cadmium sulfide nanocomposite spheres in the 50 – 300 nm size regime. This methodology uses water-in-oil microemulsions as the reaction medium. Monosize silica colloids are first produced by the controlled hydrolysis of tetraethyl orthosilicate in the micro water droplets of the microemulsion. Cadmium sulfide quantum dots are incorporated into the silica colloids during synthesis by the introductions of Cd2+ and S2- microemulsions. Various morphologies of the nanocomposite are fabricated by controlling the heterogeneous coagulation of CdS and SiO2. Unique high surface area silica particles can be prepared when nitric acid etches out the CdS and leaves behind topologically defined voids. The CdS nanocomposites are new materials useful for non-linear optics, while the high surface area silica particles should have novel applications in areas such as catalysis.

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References

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1 Matijevic, E., Langmuir 2, 12 (1986).
2 Asher, S.A., U.S. Patent No. 4 627 689 (1986).

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