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Preparation and Phase Relations in the CuSbSe2 – CuInSe2 System

  • Barys V. Korzun (a1), Valery R. Sobol (a1), Marin Rusu (a2), Ruben M. Savizky (a3), Alena A. Fadzeyeva (a4), Ivan I. Maroz (a4), Andrei N. Gavrilenko (a5), Vadim L. Matukhin (a5) and Martha Ch. Lux-Steiner (a2)...

Abstract

The CuInSe2 and CuSbSe2 ternary compounds and alloys of the (CuSbSe2)1-x·(CuInSe2)x system with the mole fraction of CuInSe2 (x) equal to 0.05, 0.15, 0.25, 0.375, 0.50, 0.625, 0.75, 0.85, and 0.95 were prepared and the phase relations in this system were investigated by X-ray powder diffraction, optical microscopy, and scanning electron microscopy. It was shown that the alloys of the CuSbSe2-CuInSe2 system are biphasic at room temperature in the whole range of compositions, and the limits of solubility for CuSbSe2 in CuInSe2 and for CuInSe2 in CuSbSe2 do not exceed 0.001 mole fraction.

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1. Wolden, C.A., Kurtin, J., Baxter, J.B., Repins, I., Shaheen, S.E., Torvik, J.T., Rockett, A.A., Fthenakis, V.M., and Aydil, E.S., J. Vac. Sci. Technol. A 29, 030801, 62 p. (2011)
2. Kumar, M., Persson, C., Energy Procedia 44, 176 (2014)
3. Dufton, J.T.R., Walsh, A., Panchmatia, P.M., Peter, L.M., Colombara, D., Islam, M.S., Phys. Chem. Chem. Phys. 14, 7229 (2012)
4. Korzun, B.V., Fadzeyeva, A.A., and Maroz, I.I., Phys. Status Solidi C 6, 1047 (2009)
5. Korzun, B.V., Gavrilenko, A.N., Fadzeyeva, A.A., Ignatenko, O.V., Maroz, I.I., Sobol, V.R., Rusu, M., Klenk, R., Merschjann, C., Schedel-Niedrig, Th., Lux-Steiner, M. Ch., Cryst. Res. Technol. 48, 641 (2013)
6. Kuliev, R.A., Krestovnikov, A.N., Glazov, V.M., Zhurnal fizicheskoi chimii XLIII, 3063 (1969) (in Russian)
7. Scott, W., Kench, J.R., Mat. Res. Bull. 8, 1257 (1973)
8. Pfitzner, A., Z. anorg. Allg. Chem. 621, 685 (1995) (in German)
9. Wernick, J.H., Benson, K.E., J. Phys. Chem. Solids 3, 157 (1957)
10. Garin, J., Parthé, E., Acta Crystallogr. B 28, 3672 (1972)
11. Pfitzner, A., Z. Kristallogr. 209, 685 (1994)
12. Zhang, Y., Ozoliņš, V., Morelli, D., Wolverton, C., Chem. Mater. 26, 3427 (2014)
13. Golovei, M.I., Tkachenko, V.I., Rigan, M.Y., Stasyuk, N.P., Izvestiia Akademii nauk SSSR. Neorganicheskie materialy 26, 933 (1990) (in Russian)
14. Imamov, R.M., Pinsker, Z.G., Ivchenko, A.I., Kristallografiya 19, 853 (1964) (in Russian)
15. Korzun, B.V., Fadzeyeva, A.A., in Proceedings of the International Conference “Actual Problems of Physics of Solids,” edited by Olekhnovich, N.M. (Minsk, Belarus, 2007), Minsk, 2007, Vol. 2, pp. 274275
16. Zhou, J., Bian, G.-Q., Zhu, Q.-Y., Zhang, Y., Li, C.-Y., Dai, J., J. Solid State Chem. 182, 259 (2009)
17. Yang, C., Wang, Y., Li, S., Wan, D., Huang, F., J. Mater. Sci. 47, 7085 (2012)

Keywords

Preparation and Phase Relations in the CuSbSe2 – CuInSe2 System

  • Barys V. Korzun (a1), Valery R. Sobol (a1), Marin Rusu (a2), Ruben M. Savizky (a3), Alena A. Fadzeyeva (a4), Ivan I. Maroz (a4), Andrei N. Gavrilenko (a5), Vadim L. Matukhin (a5) and Martha Ch. Lux-Steiner (a2)...

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