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Polar-fluoropolymer Blends for High Energy Density Low Loss Capacitor Applications

  • Shan Wu (a1) (a2), Minren Lin (a2), David S-G. Lu (a2) and Qiming Zhang (a1) (a2) (a3)


Besides energy density, the electric loss at high electric fields is another major concern for many capacitor applications. This paper presents recent works in developing high energy density low loss polymer capacitors. In order to reduce the dielectric loss while maintaining high energy density in poly(vinylidene fluoride-hexafluoropropylene) P(VDF-HFP) and P(VDF-CTFE) (CTFE: Chlorotrifluoroethylene) based polymers, a polymer blend approach was investigated. We show that by blending P(VDF-CTFE) with a proper low loss polymer such as poly(ethylene- chlorotrifluoroethylene) (ECTFE) can lead to marked improvement in the loss of dielectric films. In this study, P(VDF-CTFE) blends films with different wt% of ECTFE have been examined to find a balance between dielectric constant and the loss. In addition, crosslink in the blends has been employed to further improve the dielectric performance of the blends. The results indicate that these blends exhibit an excellent performance: relatively high dielectric constant (~ 6~7) and low loss (~ 0.01) at 1 kHz. For the crosslink blend films, the high field loss is reduced to below 5% with a discharged energy density 4.3 J/cm3 under a field of 300 MV/m.



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1. Chu, B., Zhou, X., Ren, K., Neese, B., Lin, M. R., Wang, Q., Bauer, F., and Zhang, Q. M., Science 313, 334 (2006).
2. Chu, B., Zhou, X., Neese, B., Zhang, Q. M., and Bauer, F., IEEE trans. Dielectr. Electr. Insul. 13, 1162 (2006).
3. Zhou, X., Chu, B., Neese, B., Lin, M. R., and Zhang, Q. M., IEEE trans. Dielectr. Electr. Insul. 14, 1133 (2007).
4. Zhou, Xin, Zhao, Xuanhe, Suo, Zhigang, Zou, Chen, Runt, James, Liu, Sheng, Zhang, Shihai, and Zhang, Q. M.. Appl. Phys. Lett. 94, 162901 (2009).
5. Li, Z., Wang, Y., and Cheng, Z.-Y., Appl. Phys. Lett. 88, 062904 (2006).
6. Chu, B., Neese, B., Lin, M. R., Lu, S.-G., and Zhang, Q. M., Appl. Phys. Lett. 93, 152903 (2008).
7. Li, Z., Arbatti, M. D., and Cheng, X. Y., Proc. SPIE 5385, 99 (2004).
8. Zhang, S., Neese, B., Ren, K., Chu, B., and Zhang, Q. M., J. Appl. Phys. 100, 044113 (2006).
9. Nalwa, H. S., Ed. Ferroelectric Polymers (Marcel Dekker, Inc. NY 1995).
10. Casalini, R., Roland, C. M., Appl. Phys. Lett. 79, 16 (2001).
11. Casalini, R., Roland, C. M., Journal of Polymer Science Part B: Polymer Physics, 40, 18 (2002).
12. Liang, S., Claude, J., Xu, K., and Wang, Q., Macromolecules, 41, 62656268 (2008).
13. Sinha, J. K., J. Sci. Instrum. 42, 696 (1965).
14. Zhang, Q. M., Bharti, V., and Zhao, X., Science, 280, 2001 (1998).
15. Zhang, Q. M., Huang, C., Xia, F., Su, J., and Bar-cohen, Y., SPIE Press, Bellingham, WA, 2004.
16. Xia, F., Cheng, Z., Xu, H., Li, H., Zhang, Q. M., Kavarnos, G., Ting, R., Abdul-Sedat, G., and Belfield, J., Adv. Mater., 14, 1574 (2002).


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Polar-fluoropolymer Blends for High Energy Density Low Loss Capacitor Applications

  • Shan Wu (a1) (a2), Minren Lin (a2), David S-G. Lu (a2) and Qiming Zhang (a1) (a2) (a3)


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