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Pillaring of Layered Double Hydroxides With Cage-Like Polysilicates: a Possible New Class of Base Catalysts or Catalyst Precursors

Published online by Cambridge University Press:  21 February 2011

Colin A. Fyfe
Affiliation:
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, Canada V6T 1Z1
Guoyi Fu
Affiliation:
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, Canada V6T 1Z1
Hiltrud Grondey
Affiliation:
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, Canada V6T 1Z1
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Abstract

Pillaring of highly basic layered double hydroxides (MgnAl(OH)2n+2Cl, n=2–5) with octameric polysilicate (Si8O208-) has been achieved via a direct ion exchange route.

Type
Research Article
Copyright
Copyright © Materials Research Society 1998

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References

REFERENCES

1 Cavani, F., Trifiro, F. and Vaccari, A., Catalysis Today 11, 173 (1991).Google Scholar
2 Reichle, W.T., Chemtech. 58 (1986).Google Scholar
3 De Roy, A., Forano, C., El Malki, K. and Besse, J.-P., in Synthesis of Microporous Materials Vol. II;. edited by Occelli, M.L. and Robson, H. (Van Nostrand Reinhold, New York, 1992), pp. 108169.Google Scholar
4 Jones, W and Chibwe, M., in Pillared Layered Structures, edited by Mitchell, I.V. (Elsevier Applied Science, London, 1990), pp. 6777.Google Scholar
5 Pinnavaia, TJ., Kwon, T. and Yun, S.K., NATO ASI Series, Ser. C. 352, 91 (1992).Google Scholar
6 Engelhardt, G. and Michel, D., High-Resolution Solid-State NMR of Silicates and Zeolites. (John Wiley & Sons, Chichester, 1987), pp. 75105.Google Scholar
7 Smolin, Yu.I., Shepelev, Yu.F., Pomes, R., Hoebbel, D. and Wieker, W., Sov. Phys. Crystallogr. 24, 19 (1979); M.Wiebcke, M.Grube, H.Koller, G.Engelhardt and J.Felsche, J. Microporous Mater. 2,55 (1993).Google Scholar
8 Drezdon, M.D., Inorg. Chem. 27, 4628 (1988).Google Scholar
9 Reichle, W.T., J. Cat 94, 547 (1985); C.P.Kelkar, A. Schutz and G.Marcelin, in Perspectives in Molecular Sieve Science, edited by W.F.Flank and T.E.WhyteJr., (ACS, Washington, 1988), pp. 324–334.Google Scholar