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Open-Framework Solids with Diamond-Like Structures Prepared from Clusters and Metal-Organic Building Blocks

Published online by Cambridge University Press:  28 February 2011

Omar M. Yaghi ,
D. A. Richardson ,
G. Li ,
C. E. Davis  and
T. L. Groy
Omar M. Yaghi
Affiliation:
Department of Chemistry and Biochemistry, Goldwater Center for Science and Engineering, Arizona State University, Tempe, Arizona 85287, USA
D. A. Richardson
Affiliation:
Department of Chemistry and Biochemistry, Goldwater Center for Science and Engineering, Arizona State University, Tempe, Arizona 85287, USA
G. Li
Affiliation:
Department of Chemistry and Biochemistry, Goldwater Center for Science and Engineering, Arizona State University, Tempe, Arizona 85287, USA
C. E. Davis
Affiliation:
Department of Chemistry and Biochemistry, Goldwater Center for Science and Engineering, Arizona State University, Tempe, Arizona 85287, USA
T. L. Groy
Affiliation:
Department of Chemistry and Biochemistry, Goldwater Center for Science and Engineering, Arizona State University, Tempe, Arizona 85287, USA
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Abstract

The tetrahedral cluster Ge4S104- and the rodlike ligand 4,4′-bipyridine are utilized in addition copolymerization reactions with the metal (II) ions of Mn, Fe, Co, Cu, and Zn in the preparation of 3-D open-framework solids, MxCol-xGe4S10-2(CH3)4N (x = 0.86, M = Mn; x = 1, M = Mn, Fe, Co, and Zn), 1, and Cu(4,4′-bpy)2. PF6, 2, having diamond-like structures. These structures are viewed in terms of the cubic diamond structure, where the carbon atoms have been replaced by either a cluster or a metal ion and the C-C bond by a sulfide or the 4,4′-bpy. These compounds have been fully characterized by single crystal x-ray crystallography and their composition was confirmed by elemental analysis; they contain 3-D channel systems where cations or anions reside to balance the charge on the framework.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 371: Symposium W1 – Advances in Porous Materials , 1994 , 15
Copyright
Copyright © Materials Research Society 1995

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References

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