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A Novel Approach for the Preparation of InP Nanocrystals

Published online by Cambridge University Press:  01 February 2011

Zhaoyong Sun
Affiliation:
jfang1@uno.edu, UNIVERSITY OF NEW ORLEANS, CHEMISTRY, 2000 LAKESHORE DR, NEW ORLEANS, LA, 70148, United States
Jun Zhang
Affiliation:
JZHANG3@UNO.EDU, UNIVERSITY OF NEW ORLEANS, NEW ORLEANS, LA, 70148, United States
Ming Zhang
Affiliation:
MZANG1@UNO.EDU, UNIVERSITY OF NEW ORLEANS, NEW ORLEANS, LA, 70148, United States
Jiye Fang
Affiliation:
JFANG1@UNO.EDU, UNIVERSITY OF NEW ORLEANS, NEW ORLEANS, LA, 70148, United States
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Abstract

III-V semiconductor nanocrystals are of considerable interest due to their extensive applications in the optoelectronic and biomedical fields. In order to meet the practical use, the convenient and scalable production of III-V narrow-disperse nanocrystals is inspiring. We report an efficient and rapid method of preparing highly monodisperse InP nanocrystals using a wet-chemical redox synthetic approach with a noncoordinating solvent, employing organic reducing agent LiBH(CH2CH3)3 and yellow phosphor. As advantages of this approach, reaction temperature is relatively low (80°C-120°C) and reaction time is less than 2 hours. Our characterization shows that the photoluminescence properties of InP nanocrystals are highly dependent on the particle size.

Type
Research Article
Copyright
Copyright © Materials Research Society 2006

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