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NMR chemical shift of single-wall carbon nanotubes

Published online by Cambridge University Press:  15 March 2011

Sylvain Latil ,
Christopher Goze ,
Goze Bac ,
Patrick Bernier ,
Luc Henrard  and
Angel Rubio
Sylvain Latil
Affiliation:
Groupe de Dynamique des Phases Condensées, CNRS-Université de Montpellier 2, France
Christopher Goze
Affiliation:
Groupe de Dynamique des Phases Condensées, CNRS-Université de Montpellier 2, France
Goze Bac
Affiliation:
Groupe de Dynamique des Phases Condensées, CNRS-Université de Montpellier 2, France
Patrick Bernier
Affiliation:
Groupe de Dynamique des Phases Condensées, CNRS-Université de Montpellier 2, France
Luc Henrard
Affiliation:
Laboratoire de Physique du Solide, Facultés Universitaries Notre-Dame de la Paix, Namur, Belgium
Angel Rubio
Affiliation:
Donostia International Physics Center (DIPC) and Centro Mixto CSIC-UPV, 20018 San Sebastián/Donostia, Basque Country, Spain and Departamento de Física Teórica, Universidad de Valladolid, Spain
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Abstract

We report calculation of the NMR chemical shift anisotropy (CSA) tensor →μ of single-wall carbon nanotubes, within the London approximation (ring currents contribution). Our results indicate that the isotropic line as measured by high resoultion experiments is splited about 11ppm between metallic and semiconductor nanotubes. We carefully check that this result remains vaild and observable when the bundle packing is taken into account. The resulting broadening is aroune 20ppm, but reduces onto a sharp lorentzian (<1ppm) when averaging by high resoultion NMR measurements.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 633: Symposium A – Nanotubes and Related Materials , 2000 , A14.13
Copyright
Copyright © Materials Research Society 2001

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