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New Surface Atomic Structures for III-V(110)-p(1x1)-Sb(1ML):Chemical Bonding and Electronic Structure
Published online by Cambridge University Press: 16 February 2011
Abstract
Tight-binding total energy computations are used to examine the chemical bonding and electronic structure for two new minimum-energy surface atomic structures for p(lxl) overlayers of Sb on III-V(110) surfaces. The bonding in each of these structures is unique, having no analog in either the bulk or small molecule coordination chemistry of these materials, and is a phenomenon uniquely associated with the constrained epitaxical growth of the Sb overlayer.
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