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New Magnetic Metallic Glasses with Reduced Metalloid Content

Published online by Cambridge University Press:  15 February 2011

R. C. O'handley
Affiliation:
MIT, Cambridge, MA 02139
N. J. Grant
Affiliation:
MIT, Cambridge, MA 02139
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Abstract

Several new magnetic amorphous alloys containing early transition metals (TE) and having reduced metalloid (M) content have been melt spun. Some properties of three examples of this new class, 1) Co80Nb14B6, 2) Co84Nb10B6, and 3) Fe81Nb5B14, are presented. The dominant late transition meta1 (TL) content assures an appreciable magnetic moment while the presence of an early transition metal significantly enhances the stability against crystallization. Crystallization temperatures are 1) 742K, 2) 698K, and 3) 762K for the three alloys, respectively. X-ray diffraction patterns show the materials to be amorphous and to exhibit a large-r correlation length (approximately 2.0 A) that is shorter than is typiclly observed in TL80M20 glasses containing more than one transition meta) species (approximately 2.3 − 2.5A). The coercivities of the glassy compositions range from 30 to 70 m0e.

Type
Research Article
Copyright
Copyright © Materials Research Society 1982

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References

REFERENCES

1.Polk, D. E. and Giessen, B. C., U.S. Patent N. 4,116,682, Sept. 26, 1978, Amorphous Metallic Alloys and Products Thereof.Google Scholar
2.Buschow, K.H.J. and Beckmans, N.M., Phys. Rev. B 12, 3843 (1979),Google Scholar
2aNose, M. and Masumoto, T., Sci. Rept. RITU A 28 Suppl., 222 (1980).]Google Scholar
3.Stadelmaier, H.H. and Schobel, J.D., METALL 20, 31 (1966).Google Scholar
4.Stadelmaier, H.H. and Hafer, G., METALL 18, 460 (1964).Google Scholar
5.Stacalmaier, H.H., Schobel, J.D. and Jones, R.A. METALL 21, 17 (1967).Google Scholar
6.Pearson, W.B., Crystal Chemistry and Physics of Metals and Alloys (John Wiley and Sons, New York, 1972) p748.Google Scholar
7.Polk, D. E. and Giessen, B. C., in Metallic Glasses Ed, Gilman, J.J. and Leamy, H.J., ASM Metals Park, 0, 1978, p 1.Google Scholar
8. Other Co-Nb-B glasses are reported in R.C. O'Handley, B. Corb and N.J. Grant, to be published.Google Scholar
9. Ref. 6 above, p 151.Google Scholar
10.Donald, I.W. and Davies, H.A., Phil. Mag. 42, 277 (1980).Google Scholar
11.Cargill, G.S. III, in Solid State Physics 29 ed. Ehrenreich, H., Seitz, F. and Turnbull, D. (Academic Press, New York, 1975) p 227.Google Scholar
12.Hasegawa, R. and Ray, R., J. Appl. Phys. 49, 4174, (1978).Google Scholar
13.Hasegawa, R. and Ray, R., J. Appl. Phys. 50, 1586, (1979).Google Scholar
14.Inoue, A., Masumoto, T., Kikuchi, M. and Minemura, T., Jour. JIM 42, 294 (1978).Google Scholar
15. More details concerning the magnetic properties of these glasses can be found in R.C. O'Handley, N.J. Grant, and W. Hines, to be published.Google Scholar
16.O'Handley, R. C. and Sullivan, M. O., J. Appl. Phys. 52, 1814, (1981).Google Scholar