Hostname: page-component-8448b6f56d-wq2xx Total loading time: 0 Render date: 2024-04-24T13:09:55.300Z Has data issue: false hasContentIssue false
  • English
  • Français

Nanoindentation Measurements of Mechanical Properties of Polystyrene Thin Films

Published online by Cambridge University Press:  17 March 2011

Min Li ,
C. Barry Carter  and
William W. Gerberich
Min Li
Affiliation:
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455
C. Barry Carter
Affiliation:
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455
William W. Gerberich
Affiliation:
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, MN 55455
Get access

Abstract

The elastic modulus and work of adhesion of thin polystyrene (PS) films have been evaluated from nanoindentation load-displacement curves. The modulus was calculated using two methods: an unloading stiffness analysis and an elastoplastic unloading analysis. Results indicate that the latter analysis gives better modulus evaluation for the polymers. Two methods were also utilized in determining the work of adhesion, one using the pull-off forces and one using the displacement difference at zero force and pull-off force. The values given by the two methods are close. The effects of surface roughness and maximum load on the adhesion measurements are discussed. Different molecular weights were also chosen to compare the characteristics of the polymers during use under the same conditions. No significant difference in either modulus or adhesion energy was shown between the PSs of very low, moderate, and high molecular weights at room temperature.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 649: Symposium Q – Fundamentals of Nanoindentation & Nanotribology II , 2000 , Q7.21
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Doerner, M. F. and Nix, W. D., J. Mater. Res. 1, 601 (1986).Google Scholar
2. Oliver, W. C. and Pharr, G. M., J. Mater. Res. 7, 1564 (1992).Google Scholar
3. Gerberich, W. W., Yu, W., Kramer, D., Strojny, A., Bahr, D., Lilleodden, E., and Nelson, J., J. Mater. Res. 13, 421 (1998).Google Scholar
4. Johnson, K. L., Kendall, K., and Roberts, A. D., Proc. R. Soc. Lond. A 324, 301 (1971).Google Scholar
5. Fox, T. G. and Flory, P. J., J. Appl. Phys. 21, 581 (1950).Google Scholar
6. Nielsen, L. E. and Landel, R. F., Mechanical Properties of Polymers and Composites (Marcel Dekker, Inc., New York, 1994), p. 18.Google Scholar
7. Bushan, B., Kulkarni, A. V., Bonin, W. A., and Wyrobek, T., Phil. Mag. A 74, 1117 (1996).Google Scholar
8. Polymer Handbook; edited by Brandrup, J. and Immergut, E. H. (Wiley-Interscience, New York, 1989), p. V/91.Google Scholar
9. Xia, X., Ph.D. Thesis, University of Minnesota, 2000.Google Scholar
10. Creton, C., Brown, H. R., and Shull, K. R., Macromolecules 27, 3174 (1994).Google Scholar
11. Falsafi, A., Deprez, P., Bates, F. S., and Tirrell, M., J. Rheology 41, 1349 (1998).Google Scholar
12. Li, J. C. M., Submitted to J. Mat. Sci. Eng. A (2000).Google Scholar
13. Johnson, K. L., Contact Mechanics (Cambridge University Press, Cambridge, 1987), p. 405–421.Google Scholar
14. Luengo, G., Pan, J., Heuberger, M., and Israelachvili, J. N., Langmuir 14, 3873 (1998).Google Scholar
15. LeGrand, D. G. and Gaines, G. L. Jr., J. Colloid Interface Sci. 31, 162 (1969).Google Scholar
16. Wu, S., J. Macromol. Sci. Rev. Macromol. Chem. C10, 1 (1974).Google Scholar