Hostname: page-component-7bb8b95d7b-5mhkq Total loading time: 0 Render date: 2024-09-26T16:45:59.327Z Has data issue: false hasContentIssue false

MOCVD Growth of GaN on bulk AlN Substrates

Published online by Cambridge University Press:  10 February 2011

Hong-Qiang Lu
Affiliation:
luh@rpi.edu
Ishwara B. Bhat
Affiliation:
Center for Integrated Electronics and Electronics Manufacturing, Rensselaer Polytechnic Institute, Troy, NY 12180-3590.
Byung-Chan Lee
Affiliation:
Center for Integrated Electronics and Electronics Manufacturing, Rensselaer Polytechnic Institute, Troy, NY 12180-3590.
Glen A. Slack
Affiliation:
Center for Integrated Electronics and Electronics Manufacturing, Rensselaer Polytechnic Institute, Troy, NY 12180-3590.
Leo J. Schowalter
Affiliation:
Center for Integrated Electronics and Electronics Manufacturing, Rensselaer Polytechnic Institute, Troy, NY 12180-3590.
Get access

Abstract

In this paper, the growth of epitaxial GaN layers on c-plane and a-plane bulk AIN substrates by metalorganic vapor phase epitaxy is reported. The AlN boules were grown by the sublimationrecondensation technique. Single crystal GaN films grown on the c-plane orientation replicate the substrate orientation. However the surface of the epilayer had a high density of cross-hatch defect lines, presumably caused by mechanical polishing damage. The low temperature PL spectra of these films were dominated by exciton emission at 3.470 eV with a FWHM of 14 meV at 7 K. On the other hand, GaN grown on the a-plane orientation AlN was polycrystalline and the surface was rough with ridge-like facets. The PL from this film showed a dominate peak at 3.406 eV which may originate from defect-bound excitons. The quality of the GaN layers grown on these AIN bulk substrates appeared to be limited by the surface preparation method, which has not been optimized.

Type
Research Article
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Sasaki, T., and Matsuoka, T., J. Appl. Phys. 77, 192 (1995).Google Scholar
2. Akasaki, I., Amano, H., Koide, Y., Hiramatsu, K., and Sawaki, N., J. Cryst. Growth 98, 209 (1989).Google Scholar
3. Yoshida, S., Misawa, S., and Gonda, S., Appl. Phys. Lett. 27, L1384 (1988).Google Scholar
4. Powell, R. C., Lee, N. E., Kim, Y. W., Greene, J. E., J. Appl. Phys. 73, 189 (1993).Google Scholar
5. Sasaki, T., and Matsuoka, T., J. Appl. Phys. 64, 4531 (1988).Google Scholar
6. Lin, M. E., Serdlov, S., Zhou, L., Morkoc, H., Appl. Phys. Lett. 62, 3479 (1993).Google Scholar
7. Warren, T. W. Jr., Bremser, M. D., Ailey, K. S., Carlson, E., Perry, W. G., and Davis, R. F., Appl. Phys. Lett. 67, 401 (1995).Google Scholar
8. Slack, G. A., and McNelly, T. F., J. Cryst. Growth 42, 560 (1977).Google Scholar
9. The polarity of the AIN surface was determined using the AIN piezoelectric effect.Google Scholar
10. Ogino, T., and Aoki, M., Jpn. J. Appl. Phys. 19, 2395 (1980).Google Scholar
11. Morkoc, H., Mater. Sci. Forum 239241, 119 (1997).Google Scholar
12. Sasaki, T., and Zembutsu, S., J. Appl. Phys. 61, 2533 (1987).Google Scholar
13. Pankove, J. I., Berkeyheiser, J. E., Maruska, H. P., and Wittke, J., Solid State Commun. 8, 1051 (1970).Google Scholar
14. Dingle, R., Sell, D. D., Stokowski, S. E., and Ilegems, M., Phys. Rev. B 4, 1211 (1971).Google Scholar
15. Ilegems, M., and Dingle, R., J. Appl. Phys. 44, 4234 (1973).Google Scholar
16. Hong, C. H., Pavlidis, D., Brown, S. W., and Rand, S. C., J. Appl. Phys. 77, 1706(1995).Google Scholar
17. Wetzel, C., Fisher, S., Kruger, J., Hailer, E. E., Monlar, R. J., Moustakas, T. D., Mokhov, E. N., and Baranov, P. G., Appl. Phys. Lett. 68, 2556 (1996).Google Scholar