Skip to main content Accessibility help
×
Home

Magnetic Properties Of Iron/Silica Gel Nanocomposites

  • Robert D. Shull (a1), Joseph J. Ritter (a1), Alexander J. Shapiro (a1), Lydon J. Swartzendruber (a1) and Llawrence H. Bennett (a1)...

Abstract

Homogeneous gelled composites of iron and silica containing 5–30 wt. % Fe have been prepared by low temperature polymerization of aqueous solutions of ferric nitrate, tetraethoxysilane, and ethanol (with an HF catalyst). X-ray diffraction data, characterized by the presence of a diffuse scattering peak centered at 20≈24 degrees and the absence of any strong Bragg scattering from the iron-containing regions, indicates that these bulk materials are comprised of nanometer-sized regions of iron compounds embedded in a silica gel matrix. Scanning electron microscopy observations show that this matrix is characterized by the presence of many interconnected pores and that the size of these pores is related to the particle size of the Fe-containing regions. The paramagnetic nature of these materials at room temperature, as well as the small size of the iron-containing regions, is indicated by the appearance in many of the samples of only a high intensity central doublet in the 57Fe M6ssbauer spectra. The Mössbauer effect data demonstrates that the form of the iron can be changed by a subsequent treatment in an atmosphere of ammonia or hydrogen at elevated temperatures: for a 10 wt. % Fe sample treated with ammonia, only a central doublet was observed but with a much larger quadrupole splitting and isomer shift. Both of these subsequently treated materials became superparamagnetic at room temperature. In addition, magnetic susceptibility measurements indicate that the hydrogen treated material becomes a spin glass at low temperatures.

Copyright

References

Hide All
[1] Abeles, B., Appl. Solid State Sci. 6, 1 (1976).
[2] Bilisoly, J. P., U.S. Patent No. 2496265 (Feb. 7, 1950).
[3] Roy, R. A. and Roy, R., Mat. Res. Bull. 19, 169 (1984).
[4] Pope, E. J. A. and Mackenzie, J. D., J. Non-Crys. Sol. 87, 185 (1986).
[5] Xiao, Gang, Liou, S. H., Levy, A., Taylor, J.N., and Chien, C. L., Phys. Rev. B 34, 7573 (1986).
[6] Kundig, W., Bommel, H., Constabaris, G., and Lindquist, R., Phys. Rev. 142, 327 (1966).
[7] Shull, R. D., Atzmony, U., Shapiro, A. J., Swartzendruber, L. J., Bennett, L. H., Green, W. J., and Moorjani, K., J. Appl. Phys. 63, 4261 (1988).
[8] Mukhopadhyay, A. K., Shull, R. D., and Beck, P. A., J. Less Common Metals 43, 69 (1975).

Magnetic Properties Of Iron/Silica Gel Nanocomposites

  • Robert D. Shull (a1), Joseph J. Ritter (a1), Alexander J. Shapiro (a1), Lydon J. Swartzendruber (a1) and Llawrence H. Bennett (a1)...

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 0 *
Loading metrics...

Abstract views

Total abstract views: 0 *
Loading metrics...

* Views captured on Cambridge Core between <date>. This data will be updated every 24 hours.

Usage data cannot currently be displayed