Hostname: page-component-76fb5796d-22dnz Total loading time: 0 Render date: 2024-04-25T12:45:38.989Z Has data issue: false hasContentIssue false

Long-Term Degradation Mechanism of Organic Light Emitting Devices Based on Small Molecules

Published online by Cambridge University Press:  10 February 2011

Hany Aziz
Affiliation:
Department of Materials Science & Engineering, McMaster University, Hamilton, Ontario, Canada, L8S 4L7, azizhm@mcmaster.ca
Zoran D. Popovic
Affiliation:
Xerox Research Centre of Canada, Mississauga, Ontario, Canada, L5K 2L1
Nan-Xing Hu
Affiliation:
Xerox Research Centre of Canada, Mississauga, Ontario, Canada, L5K 2L1
Ah-Mee Hor
Affiliation:
Xerox Research Centre of Canada, Mississauga, Ontario, Canada, L5K 2L1
Gu Xu
Affiliation:
Department of Materials Science & Engineering, McMaster University, Hamilton, Ontario, Canada, L8S 4L7
Get access

Abstract

The intrinsic degradation of tris(8-hydroxyquinoline) aluminum (AlQ3)-based organic light emitting devices, that leads to the long-term decrease in the electroluminescence efficiency of the devices operated under constant current conditions, is studied. The injection of holes in A1Q3 is found to be the main factor responsible for device degradation. OLEDs with dual HTLs in different arrangements are also presented to demonstrate the proposed degradation mechanism. The role of various approaches to increase OLED lifetime, such as, doping the hole transport layer, introducing a buffer layer at the hole-injecting contact, or using a mixed emitting layer of hole and electron transporting molecules, is explained.

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Tang, C. W., Slyke, S. A. Van, Chen, C. H., Appl. Phys. Lett. 65, 3610 (1989).Google Scholar
2. Kido, J. and Iizumi, Y., Appl. Phys. Lett. 73, 2721 (1998).Google Scholar
3. Shen, Z., Burrows, P. B., Bulovic, V., Forrest, S. R., Thompson, M. E., Science 276, 2009 (1997).Google Scholar
4. Sheats, J.R., Antoniadis, H., Hueschen, M., Leonard, W., Miller, J., Moon, R., Roitman, D. and Stocking, A., Science 273, 884 (1996).Google Scholar
5. McElvain, J., Antoniadis, H., Hueschen, M. R., Miller, J. N., Roitman, D. M., Sheets, J. R. and Moon, R. L., J. Appl. Phys. 80, 6002 (1996).Google Scholar
6. Aziz, H., Popovic, Z., Xie, S., Hor, A., Hu, N., Tripp, C. and Xu, G., Appl. Phys. Lett. 72, 756 (1998), H. Aziz, Z. Popovic, C. P. Tripp, N. Hu, A. Hor and G. Xu, ibid., p. 2642.Google Scholar
7. Burrows, P. E., Bulovic, V., Forrest, S. R., Sapochak, L. S., McCarty, D. M. and Thompson, M. E.., Appl. Phys. Lett. 65, 2922 (1994).Google Scholar
8. , Hamada, Sano, T., Shibata, K., Kuroki, K., Jpn. J. Appl. Phys. 34, L824, (1995).Google Scholar
9. Slyke, S. A. Van, Chen, C. H., Tang, C. W., Appl. Phys. Lett. 69, 2160 (1996).Google Scholar
10. Shi, J. and Tang, C. W., Appl. Phys. Lett. 70, 1665 (1997).Google Scholar
11. Adachi, C., Nagai, K., Tamoto, N., Appl. Phys. Lett. 66, 2679 (1995).Google Scholar
12. Popovic, Z. D., Aziz, H., Tripp, C. P., Hu, N. X., Hor, A. M.. and Xu, G.., in roceedings of the SPIE, Volume 3476, Organic Light-Emitting Materials and Devices II, San Diego, CA, July 1998, pp 6873.Google Scholar
13. Vestweber, H. and Rieb, W., Synth. Met. 91, 181 (1997).Google Scholar
14. Yang, J. and Shen, J., J. Appl. Phys. 84, 2105 (1998).Google Scholar
15. Malliaras, G. G. and Scott, J. C., J. Appl. Phys. 83, 5399 (1998).Google Scholar
16. Papadimitrakopoulos, F., Zhang, X.-M., Thomsen, D. L. III, Higginson, K. A., Chem. Mater. 8, 1363 (1996).Google Scholar
17. Aziz, H., Popovic, Z. D., Hu, N. X., Hor, A. M. and Xu, G., Science 283, 1900 (1999).Google Scholar
18. Bin, L. B., Jenekhe, S. A., Young, R. H., Borsenberger, P. M., Appl. Phys. Lett. 70, 2052 (1997).Google Scholar
19. Anderson, J. D. et al. , J. Am. Chem. Soc. 120, 9646 (1998).Google Scholar